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Significance and Use
5.1 The oxidative induction time is a characteristic of a compounded polyolefin product that is dependent not only on the type and amount of additives present, but also on the type of resin. In well-behaved systems, this test method can be used as a quality control measure to monitor the stabilization in geosynthetics as received from a supplier.
5.2 When this test method is used to compare different geomembrane formulations containing different antioxidant packages, then those results shall be considered valid only at the temperature of test.
5.3 This test method is intended as an geosynthetic test. Use of the OIT value to estimate the lifetime of the geomembrane from which the test specimen is taken is not addressed nor shall it be used for this purpose.
5.3.1 The OIT measurement is an accelerated thermal aging test and, as such, interpretation of resulting data may be misleading if done by an inexperienced operator. Caution should be exercised in data interpretation since oxidation reaction kinetics are a function of temperature and the properties of the additives contained in the geosynthetic sample. For example, OIT values are often used to select optimum resin formulations. Certain antioxidants, however, may generate poor OIT results even though they may be adequate at their intended use temperature and vice versa.
5.5 Oxidation induction time is strongly dependent upon test temperature and the partial pressure of oxygen. The higher the test temperature or the oxygen partial pressure, or both, the shorter the oxidation induction time.
5.5.1 The use of high test temperature, however, may have deleterious effects. The first of these is the potential volatilization of additive packages used to stabilize the test materials. The second is the potential for the influence of chemical mechanisms which are not significant at end-use operation conditions.
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 8.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D3895 Test Method for Oxidative-Induction Time of Polyolefins by Differential Scanning Calorimetry
D4439 Terminology for Geosynthetics
D4491 Test Methods for Water Permeability of Geotextiles by Permittivity
D4565 Test Methods for Physical and Environmental Performance Properties of Insulations and Jackets for Telecommunications Wire and Cable
D4703 Practice for Compression Molding Thermoplastic Materials into Test Specimens, Plaques, or Sheets
E473 Terminology Relating to Thermal Analysis and Rheology
E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
E967 Test Method for Temperature Calibration of Differential Scanning Calorimeters and Differential Thermal Analyzers
G88 Guide for Designing Systems for Oxygen Service
ICS Number Code 59.080.70 (Geotextiles)
UNSPSC Code 30121900(Soil stabilizers and reinforcing materials)
ASTM D5885-06(2012), Standard Test Method for Oxidative Induction Time of Polyolefin Geosynthetics by High-Pressure Differential Scanning Calorimetry, ASTM International, West Conshohocken, PA, 2012, www.astm.orgBack to Top