New Practice for Measuring Stability of Glass-ceramic Solidified Body of High Level Chloride Salts Produced in Pyro-reprocessing of FR Spent Nuclear Fuels
1. Scope
This practice is applicable to provide the glass-ceramic composite method to solidify the chlorine-containing salt waste, which are generated in the pyro-reprocessing processes.
In this method, the chloride wastes are converted to the stable ceramic phases and are bounded with glass binders. Combining the advantages of higher chlorine-containing ability of ceramic and lower sintering temperature with glass, MCC-1 leaching test results show the chemical stability of glass-bound Cl-sodalite samples; and the heat treatments exhibit their thermal stability.
In comparison with spent fuels from pressurized water reactors, spent fuels from fast breeder
reactors contain much more transuranic elements and fission products, and hence are of much higher radioactivity. This makes the traditional wet reprocessing method by solvent extraction difficult and as a result the pyro-reprocessing method by molten salts was developed. In this case, high level waste salts will be produced instead of high level liquid waste.
In order to protect human beings and the environment from the danger caused by the highly water-soluble salts, proper solidification measures must be taken prior to the final geological disposal.