New Practice for Xenon Arc Exposure of Aromatic Plastics with Washing to Simulate Erosion During Outdoor Exposures
1. Scope
1. Scope
1.1 This practice specifies the operating procedures for a controlled irradiance xenon arc light and water apparatus. The procedure uses one or more lamp(s) and optical filter(s) to produce irradiance similar to sunlight in the UV and visible range. It also simulates the washing effects of rain (and wind) that remove debris left on plastic surfaces as the polymer erodes during natural outdoor weathering. This practice has also been found applicable to aromatic polymers such as. polycarbonate, polyesters, styrene-containing polymers, and various aromatic copolymers.
1.2 This practice uses a xenon arc light source with specified optical filter(s) to closely match the spectral power distribution (SPD) of sunlight in the range of 295 to 400 nm. The irradiance level used in this practice is 0.80 W/(m2·nm) at 340 nm to provide high acceleration. Water is sprayed on the specimens only in the dark and for a long duration. In addition, the specimens are manually washed with a sponge and deionized water to remove accumulated debris that natural rain apparently washes off but the gentle sprays in weathering devices do not. These test conditions are designed to reproduce the surface characteristics, such as color shift and gloss, that result from exposure in a subtropical climate, such as southern Florida. The exposure used in this practice is not intended to simulate the deterioration caused by localized weather phenomena, such as atmospheric pollution, biological attack, and saltwater exposure.
1.3 This practice is intended for use on aromatic plastic materials that exhibit erosion during outdoor weathering exposures.
1.4 This practice is not intended to cover aliphatic plastics or coatings on plastics. Plastics intended for indoor use are not covered.
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
Please find below a draft for a New Practice for the Accelerated Weathering of Aromatic Plastics. This is a designed exposure, for a specific class of materials, to reproduce a specific exposure result that happens during outdoor exposure testing.
This new practice is specifically for aromatic plastics, which due to their unique chemistry erode and can leave surface deposits such as pigment particles as part of the weathering process. The deposits are not from the atmosphere, but are formed as the material degrades. These deposits are removed when the materials are exposed outdoors, due to rainfall similar to benchmark locations such as South Florida and Arizona, and/or periodic surface washing (field rinsing) as required by many outdoor weathering standards. If these surface deposits are not removed during accelerated weathering, the continuation of weathering is different than if those deposits are removed. Different results are obtained between washed and unwashed specimens.
There is no accelerated laboratory method currently that simulates this specific effect. Xenon arc testing is extremely good at simulating the exposures, but most currently accepted cycles are lower in water spray durations, and do not include surface washing. Using a newer high moisture cycle improves correlation, and periodic washing of the specimens reproduces the erosion effect. Together these modifications give good agreement to outdoor weathering of aromatic plastics in a South Florida exposure test.
A new focused method is required to fill this need. Committee D20 is the logical place to have a specific standard for accelerated weathering of plastic material. Currently this method has only been demonstrated as effective for this combination of material type, and exposure practice. The Scope of this new practice confirms its application to this limited field of use.
Anyone interested in further information will find a full list of references at the end of the draft.