Batch sorption tests were conducted to determine the partition coefficient of volatile organic compounds (VOCs) by ground tires. The partition coefficient in the vapor phase was estimated by dividing the partition coefficient in the aqueous phase by Henry's law constant. Under a diluted condition (<0.6 mM), VOCs are sorbed onto ground tires noncompetitively regardless of the existence of other VOCs. Polar compounds such as methylene chloride were less sorbed onto ground tires than nonpolar compounds. The vapor-phase partition coefficient was found to have a logarithmic relationship with the saturation vapor concentration. VOCs emitted from waste-water treatment facilities can be effectively retarded by the ground tires.
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