SYMPOSIA PAPER Published: 01 January 1994

Phenomenological Study of In-Reactor Corrosion of Zircaloy-4 in Pressurized Water Reactors


Uniform in-reactor corrosion has been examined on pressurized water reactor (PWR) Zircaloy-4 fuel claddings that were irradiated up to four cycles in the KORI Unit 1. The oxide layer that was formed on the Zircaloy-4 fuel claddings changes from a uniform black oxide into the nonuniform white granular oxides when the oxide layer reaches about 5 to 10 μm. With irradiation exposure, enough of the white granular oxides have nucleated above the black oxide layer to entirely cover the fuel cladding, resulting in a gray or white cladding surface. The change in the oxide layer growth pattern from the uniform black oxide layer into the nonuniform granular oxides resulted in the formation of macro-pores or cracks in the oxide layer, causing the corrosion rate to change into a linear rate from the cubic rate, especially at the beginning of fuel rod life. Consequently, the nucleation of white granular oxides is a phenomenological indicator of the transition of the in-reactor corrosion rate.

To explain the effect of hydride precipitates on the in-reactor corrosion, the corrosion behavior for a defective fuel rod with a through-hole and an intact fuel rod adjacent to it (both were irradiated for two cycles in the KORI Unit 1) has been investigated. Even though both of them were found to have almost identical operating power histories, their corrosion behavior was quite different: the maximum oxide layer thickness for the intact fuel rod was less than 10 μm, while the defective fuel rod had an abnormally thick oxide of 50 μm, especially at an elevation where a large extent of hydrides (corresponding to 1295 to 1520 ppm hydrogen) were precipitated at the cladding outer surface. Therefore, the hydrides that were locally precipitated on the cladding outer surface initiated the in-reactor corrosion enhancement to a degree that was dependent upon the extent of the hydrides. Furthermore, the corrosion enhancement by hydrides is likely to effectively occur late in the fuel life time or after more than three or four cycles of irradiation, thus leading to the enhanced post-transition corrosion rate.

Author Information

Kim, YS
Korea Atomic Energy Research Institute, Yusung, Taejon, Korea
Rheem, KS
Korea Atomic Energy Research Institute, Yusung, Taejon, Korea
Min, DK
Korea Atomic Energy Research Institute, Yusung, Taejon, Korea
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Developed by Committee: B10
Pages: 745–759
DOI: 10.1520/STP15218S
ISBN-EB: 978-0-8031-5286-1
ISBN-13: 978-0-8031-2011-2