Journal Published Online: 22 March 2018
Volume 46, Issue 4

Synthesis and Performance Evaluation of Epoxy Resin–Modified Shape Memory Polyurethane Sealant

CODEN: JTEVAB

Abstract

To evaluate the effects of epoxy resin (EP) on different properties of shape memory polyurethane (SMPU) when used as a sealant with a tailored thermal transition temperature (Tt) for concrete pavement joints, the thermal and dynamic mechanical performances were discussed to determine the shape memory switching temperature of EP-modified SMPU, and then the compatibility between EP and SMPU, microscopic morphology, shape memory effect, and tensile property were also characterized. The results indicate that the tailored Tt of EP-modified SMPU can be used as the shape memory switching temperature to match its working temperature. EP and SMPU show considerable compatibility. EP inhibits the crystallization of soft phase content and increases the hard phase content. Both hydroxyl and epoxy groups participate in chemical reactions. The ring-opening reactions occur between fractional benzenes and SMPU. EP was successfully grafted onto the main chains of SMPU. Additionally, the peak load, tensile strength, and elongation at break of SMPU are first increased and then decreased when the EP content increase. An EP content of 10 % improves the tensile properties of SMPU, but excessive EP content leads to a decrease in the tensile strength and elongation at break. Finally, it is found that a small amount of EP has little influence on the shape memory properties of SMPU, but EP can improve the tensile properties of SMPU. EP-modified SMPU shows excellent shape memory effects. The prepared EP-modified SMPU with the specially tailored Tt can meet the requirements of practical engineering when used as a sealant for concrete pavement joints.

Author Information

Shen, Dongya
School of Civil Engineering, Nanjing Forestry University, Nanjing, Jiangsu, China
Shi, Shuang
School of Civil Engineering, Nanjing Forestry University, Nanjing, Jiangsu, China
Xu, Tao
School of Civil Engineering, Nanjing Forestry University, Nanjing, Jiangsu, China
Pages: 10
Price: $25.00
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Stock #: JTE20170298
ISSN: 0090-3973
DOI: 10.1520/JTE20170298