Standard Active Last Updated: Dec 10, 2021 Track Document
ASTM F22-21

Standard Test Method for Hydrophobic Surface Films by the Water-Break Test

Standard Test Method for Hydrophobic Surface Films by the Water-Break Test F0022-21 ASTM|F0022-21|en-US Standard Test Method for Hydrophobic Surface Films by the Water-Break Test Standard new BOS Vol. 15.03 Committee E21
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Significance and Use

5.1 The water-break test as described in this test method is rapid, nondestructive, and may be used for control and evaluation of processes for the removal of hydrophobic contaminants. A water-break “free” test is commonly used for in-process verification of the absence of surface contaminants on metal surfaces that may interfere with subsequent surface treatments such as priming, conversion coating, anodizing, plating, or adhesive bonding

5.2 This test method is not quantitative and is typically restricted to applications where a go/no go evaluation of cleanliness will suffice.

5.3 The test may also be used for the detection and control of hydrophobic contaminants in processing environments. For this application, a witness surface free of hydrophobic films is exposed to the environment and subsequently tested. The sensitivity of this test will vary with the level of airborne contaminant and the duration of exposure of the witness surface.

5.4 For quantitative measurement of surface wetting, test methods that measure contact angle of a sessile drop of water or other test liquid may be used in some applications. Measurement methods based on contact angle are shown in Test Methods C813, D5946, and D7490; and Practice D7334.

5.4.1 Devices for in situ measurement of contact angle are available. These devices are limited to a small measurement surface area and may not reflect the cleanliness condition of a larger surface. For larger surface areas, localized contact angle measurement, or other quantitative inspection, combined with water-break testing may be useful.

5.5 For surfaces that cannot be immersed or doused with water, or where such immersion or dousing is impractical, such as previously coated large parts or assemblies, prior to the application of paints, primers or other organic coatings, Test Method F21 may be better suited for the evaluation of surface cleanliness than this test method.

Note 2: This test method is not appropriate where line of sight evaluation is not feasible; or for assembled hardware where there is a risk for entrapment of water in faying surfaces or complex structures where it may not be effectively removed.


1.1 This test method covers the detection of the presence of hydrophobic (nonwetting) films on surfaces and the presence of hydrophobic organic materials in processing environments. When properly conducted, the test will enable detection of molecular layers of hydrophobic organic contaminants. On very rough or porous surfaces, the sensitivity of the test may be significantly decreased.

1.2 Units—The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Book of Standards Volume: 15.03
Developed by Subcommittee: E21.05
Pages: 5
DOI: 10.1520/F0022-21
ICS Code: 25.220.20