Standard Withdrawn, No replacement   Last Updated: Aug 01, 2012
ASTM E1507-98(2003)

Standard Guide for Describing and Specifying the Spectrometer of an Optical Emission Direct-Reading Instrument (Withdrawn 2003)

Significance and Use

Direct-reading polychromators are instruments commonly used for multi-element spectrochemical analysis. This guide seeks to describe those aspects of such instruments that are of significance in achieving useful spectrochemical performance. Awareness of parameters described in this practice will make manufacturers cognizant of factors they should consider in designing instruments, assist purchasers of instruments in making intelligent comparisons of competing designs, and make users aware of the compromises they must make in performing particular determinations.

Adequate description of spectrometers permits forming qualified appraisals on three important performance characteristics: accuracy of analysis, detection limits, and freedom from line interferences.


1.1 This guide covers features of a spectrometer or polychromator used for optical emission, direct-reading, spectrochemical analysis. A polychromator in this sense consists of a spectrometer with an extended and fixed wavelength range and an array of fixed exit slits to isolate the spectral lines of the elements to be measured.

1.1.1 This guide does not apply to direct-reading systems that employ echelle spectrometers and vidicon or other detectors where the design parameters are quite different.

1.2 This guide covers only the optical portion of the instrument, from excitation stand to photomultipliers.

1.2.1 Only general statements are made about source units.

1.2.2 Photomultipliers are included to the extent that they are mounted within the spectrometer to convert optical intensities to electrical signals, and establish the instrumental precision of each channel as a light measuring device. Readout systems are not included.

1.3 It is not the purpose of this guide to establish binding specifications or tolerances, but rather, to call attention to important parameters that manufacturers should include in their literature, to provide methods for measuring those parameters, and to assign values that are indicative of acceptably good performance. Because of the great variety of demands imposed by spectrochemical techniques, rigid performance criteria are not feasible.

1.4 The values stated in SI units are to be regarded as the standard.

1.5 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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