Standard Historical Last Updated: Nov 16, 2015
ASTM D7542-09

Standard Test Method for Air Oxidation of Carbon and Graphite in the Kinetic Regime

Significance and Use

This test method can be used to measure the rate of oxidation for various grades of manufactured carbon and graphite in standard conditions, and can be used for quality control purposes.

This test method also provides kinetic parameters (activation energy and logarithm of pre-exponential factor) for the oxidation reaction, and a standard oxidation temperature. The results uniquely characterize the effect of temperature on oxidation rates in air, and the oxidation resistance of machined carbon or graphite specimens with standard size and shape, in the kinetic, or chemically controlled, oxidation regime. This information is useful for discrimination between material grades with different impurity levels, grain size, pore structure, degree of graphitization, or antioxidation treatments, or a combination thereof.

5.3 Accurately determined kinetic parameters, like activation energy and logarithm of pre-exponential factor, can be used for prediction of oxidation rates in air as a function of temperature in conditions similar to those of this test method. However, extrapolation of such predictions outside the temperature range where Arrhenius plots are linear (outside the kinetic or chemically controlled regime of oxidation) should be made with caution. In conditions where oxidation rates become controlled by a mechanism other than chemical reactions, such as in-pore diffusion or boundary transport of the oxidant gas, prediction of oxidation rates using kinetic parameters determined with this test method may produce overestimated results.


1.1 This test method covers the rate of oxidative weight loss per exposed nominal geometric surface area, or per initial weight of machined test specimens of standard size and shape, or both. The test is valid in the temperature range where the rate of air oxidation of graphite and manufactured carbon is limited by reaction kinetics.

1.2 This test method also provides a standard oxidation temperature (as defined in 3.1.7), and the kinetic parameters of the oxidation reaction, namely the activation energy and the logarithm of pre-exponential factor in Arrhenius equation. The kinetic parameters of Arrhenius equation are calculated from the temperature dependence of oxidation rates measured over the temperature range where Arrhenius plots (as defined in 3.1.8) are linear, which is defined as the kinetic or chemical control oxidation regime. For typical nuclear grade graphite materials it was found that the practical range of testing temperatures is from about 500550°C up to about 700750°C.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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Book of Standards Volume: 05.05
Developed by Subcommittee: D02.F0
Pages: 12
DOI: 10.1520/D7542-09
ICS Code: 71.060.10