Standard Historical Last Updated: Nov 17, 2014
ASTM D3849-14

Standard Test Method for Carbon Black—Morphological Characterization of Carbon Black Using Electron Microscopy

Significance and Use

4.1 Carbon black morphology significantly affects the transient and end-use properties of carbon black loaded polymer systems. A carbon black's particle size distribution is its single most important property, and it relates to degree of blackness, rubber reinforcement, and ability to impart UV protection. For a given loading of carbon black, blackness, reinforcement, and UV protection increase with smaller particle size. Aggregate size and shape (structure) also affect a carbon black's end-use performance, as higher carbon black structure increases viscosity and improves dispersion. The stiffness (modulus) of elastomer systems becomes significantly higher with increasing structure. The preferred method for measuring carbon black morphology (for example, size and shape) is transmission electron microscopy (TEM), but due to the semi-quantitative nature of TEM, it is not suited for mean particle size (MPS) certification.

4.2 Carbon black aggregate dimensional and shape properties are dependent upon the nature of the system in which the sample is dispersed, as well as the mixing procedure.

Scope

1.1 This test method covers (1) the morphological (for example, size and shape) characterization of carbon black from transmission electron microscope images which are used to derive the mean particle and aggregate size of carbon black in the dry (as manufactured) state, from CAB chip dispersion or removed from a rubber compound and (2) the certification of mean particle size using a correlation based on statistical thickness surface area measurements.

1.2 The values stated in SI units are to be regarded as the standard. The values in parentheses are for information only.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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Details
Book of Standards Volume: 09.01
Developed by Subcommittee: D24.81
Pages: 8
DOI: 10.1520/D3849-14
ICS Code: 83.040.20