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Significance and Use
5.1 Atmospheric corrosion of metallic materials is a function of many weather and atmospheric variables. The effect of specific corrodants, such as sulfur dioxide, can accelerate the atmospheric corrosion of metals significantly. It is important to have information available for the level of atmospheric SO2 when many metals are exposed to the atmosphere in order to determine their susceptibility to corrosion damage during their life time in the atmosphere.
5.2 Volumetric analysis of atmospheric SO2 concentration carried out on a continuous basis is considered by some investigators as the most reliable method of estimating the effects caused by this gas. However, these methods require sophisticated monitoring devices together with power supplies and other equipment that make them unsuitable for many exposure sites. These methods are beyond the scope of this practice.
5.3 The sulfation plate method provides a simple technique to independently monitor the level of SO2 in the atmosphere to yield a weighted average result. The lead peroxide cylinder is similar technique that produces comparable results, and the results are more sensitive to low levels of SO2.
5.4 Sulfation plate or lead peroxide cylinder results may be used to characterize atmospheric corrosion test sites regarding the effective average level of SO2 in the atmosphere at these locations.
5.5 Either sulfation plate or lead peroxide cylinder testing is useful in determining microclimate, seasonal, and long term variations in the effective average level of SO2.
5.6 The results of these sulfur dioxide deposition rate tests may be used in correlations of atmospheric corrosion rates with atmospheric data to determine the sensitivity of the corrosion rate to SO2 level.
5.7 The sulfur dioxide monitoring methods may also be used with other methods, such as Practice for measuring time of wetness and Test Method for atmospheric chloride deposition, to characterize the atmosphere at sites where buildings or other construction is planned in order to determine the extent of protective measures required for metallic materials.
1.1 This practice covers two methods of monitoring atmospheric sulfur dioxide, SO2 deposition rates with specific application for estimating or evaluating atmospheric corrosivity as it applies to metals commonly used in buildings, structures, vehicles and devices used in outdoor locations.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D516 Test Method for Sulfate Ion in Water
D1193 Specification for Reagent Water
D2010/D2010M Test Methods for Evaluation of Total Sulfation Activity in the Atmosphere by the Lead Dioxide Technique
G16 Guide for Applying Statistics to Analysis of Corrosion Data
G84 Practice for Measurement of Time-of-Wetness on Surfaces Exposed to Wetting Conditions as in Atmospheric Corrosion Testing
G140 Test Method for Determining Atmospheric Chloride Deposition Rate by Wet Candle Method
ICS Number Code 13.040.20 (Ambient atmospheres)
UNSPSC Code 41114604(Corrosion testers)
|Link to Active (This link will always route to the current Active version of the standard.)|
ASTM G91-11(2018), Standard Practice for Monitoring Atmospheric SO