ASTM E2426 - 10(2019)

    Standard Practice for Pulse Counting System Dead Time Determination by Measuring Isotopic Ratios with SIMS

    Active Standard ASTM E2426 | Developed by Subcommittee: E42.06

    Book of Standards Volume: 03.06

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    Significance and Use

    5.1 Electron multipliers are commonly used in pulse-counting mode to detect ions from magnetic sector mass spectrometers. The electronics used to amplify, detect and count pulses from the electron multipliers always have a characteristic time interval after the detection of a pulse, during which no other pulses can be counted. This characteristic time interval is known as the “dead time.” The dead time has the effect of reducing the measured count rate compared with the “true” count rate.

    5.2 In order to measure count rates accurately over the entire dynamic range of a pulse counting detector, such as an electron multiplier, the dead time of the entire pulse counting system must be well known. Accurate count rate measurement forms the basis of isotopic ratio measurements as well as elemental abundance determinations.

    5.3 The procedure described herein has been successfully used to determine the dead time of counting systems on SIMS instruments.6 The accurate determination of the dead time by this method has been a key component of precision isotopic ratio measurements made by SIMS.

    1. Scope

    1.1 This practice provides the Secondary Ion Mass Spectrometry (SIMS) analyst with a method for determining the dead time of the pulse-counting detection systems on the instrument. This practice also allows the analyst to determine whether the apparent dead time is independent of count rate.

    1.2 This practice is applicable to most types of mass spectrometers that have pulse-counting detectors.

    1.3 This practice does not describe methods for precise or accurate isotopic ratio measurements.

    1.4 This practice does not describe methods for the proper operation of pulse counting systems and detectors for mass spectrometry.

    1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

    1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    E673 Terminology Relating to Surface Analysis

    ISO Standard

    ISO21270 Surface chemical analysis -- X-ray photoelectron and Auger electron spectrometers -- Linearity of intensity scale; and references 1, 2, 10, 13 and 14 therein.

    ICS Code

    ICS Number Code 71.040.50 (Physicochemical methods of analysis)

    UNSPSC Code

    UNSPSC Code 41115404(Mass spectrometers)

    Referencing This Standard
    Link Here
    Link to Active (This link will always route to the current Active version of the standard.)

    DOI: 10.1520/E2426-10R19

    Citation Format

    ASTM E2426-10(2019), Standard Practice for Pulse Counting System Dead Time Determination by Measuring Isotopic Ratios with SIMS, ASTM International, West Conshohocken, PA, 2019,

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