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Significance and Use
6.1 This test method is useful in research and development.
6.2 The determination of the appropriate model for a chemical reaction or transformation and the values associated with its kinetic parameters may be used in the estimation of reaction performance at temperatures or time conditions not easily tested. This use, however, is not described in this test method.
1.1 This test method describes the determination of the kinetic parameters of activation energy, Arrhenius pre-exponential factor, and reaction order using the Borchardt and Daniels2 treatment of data obtained by differential scanning calorimetry. This test method is applicable to the temperature range from 170 to 870 K (−100 to 600 °C).
1.2 This treatment is applicable only to smooth exothermic reactions with no shoulders, discontinuous changes, or shifts in baseline. It is applicable only to reactions with reaction order n ≤ 2. It is not applicable to acceleratory reactions and, therefore, is not applicable to the determination of kinetic parameters for most thermoset curing reactions or to crystallization reactions.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This test method is similar, but not equivalent to, ISO 11357, Part 5, that contains provisions for additional information not supplied by this test method.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
E473 Terminology Relating to Thermal Analysis and Rheology
E537 Test Method for The Thermal Stability of Chemicals by Differential Scanning Calorimetry
E698 Test Method for Arrhenius Kinetic Constants for Thermally Unstable Materials Using Differential Scanning Calorimetry and the Flynn/Wall/Ozawa Method
E967 Test Method for Temperature Calibration of Differential Scanning Calorimeters and Differential Thermal Analyzers
E968 Practice for Heat Flow Calibration of Differential Scanning Calorimeters
E1142 Terminology Relating to Thermophysical Properties
E1445 Terminology Relating to Hazard Potential of Chemicals
E1641 Test Method for Decomposition Kinetics by Thermogravimetry
E1970 Practice for Statistical Treatment of Thermoanalytical Data
ISO StandardsISO 11357 Part 5: Determination of Temperature and/or Time of Reaction and Reaction Kinetics
ICS Number Code 17.200.10 (Heat. Calorimetry)
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ASTM E2041-13e1, Standard Test Method for Estimating Kinetic Parameters by Differential Scanning Calorimeter Using the Borchardt and Daniels Method, ASTM International, West Conshohocken, PA, 2013, www.astm.orgBack to Top