If you are an ASTM Compass Subscriber and this document is part of your subscription, you can access it for free at ASTM Compass
    ASTM E1791 - 96(2021)

    Standard Practice for Transfer Standards for Reflectance Factor for Near-Infrared Instruments Using Hemispherical Geometry

    Active Standard ASTM E1791 | Developed by Subcommittee: E13.03

    Book of Standards Volume: 03.06

      Format Pages Price  
    PDF 4 $48.00   ADD TO CART
    Hardcopy (shipping and handling) 4 $48.00   ADD TO CART

    Significance and Use

    5.1 Most commercial reflectometers and spectrophotometers with reflectance capability measure relative reflectance. The instrument reading is the ratio of the measured radiation reflected from the reference specimen to the measured radiation reflected by the test specimen. That ratio is dependent on specific instrument parameters.

    5.2 National standardizing laboratories and some research laboratories measure reflectance on instruments calibrated from basic principles, thereby establishing a scale of absolute reflectance as described in CIE Publication No. 44 (5). These measurements are sufficiently difficult and of prohibitive cost that they are usually left to laboratories that specialize in them.

    5.3 A standard that has been measured on an absolute scale could be used to transfer that scale to a reflectometer. While such procedures exist, the constraints placed on the mechanical properties restrict the suitability of some of the optical properties, especially those properties related to the geometric distribution of reflected radiation. Thus, reflectance factor standards that are sufficiently rugged or cleanable to use as permanent transfer standards, with the exception of the sintered PTFE standards, depart considerably from the perfect diffuser in the geometric distribution of reflected radiation.

    5.4 The geometric distribution of reflected radiance from such standards is sufficiently diffuse that such a standard can provide a dependable calibration of a directional-hemispherical or certain directional-directional reflectometers. Although pressed powder standards are subject to contamination and breakage, the reflectance factor of pressed powder can be sufficiently reproducible from specimen to specimen from a given lot of powder to allow the assignment of absolute reflectance factor values to all of the powder in a lot.

    5.5 Sintered PTFE materials exhibit sufficient reproducibility from within the same specimen after resurfacing or cleaning the specimen to allow the assignment of absolute reflectance factor values.

    5.6 Preparation of packed powder reflectance standards is covered in Practice E259. This practice describes the spectral and physical properties of these materials and of the sintered PTFE materials.

    1. Scope

    1.1 This practice covers procedures for the preparation and use of acceptable transfer standards for NIR spectrophotometers. Procedures for calibrating the reflectance factor of materials on an absolute basis are contained in CIE Publication No. 44 (9). Both the pressed powder samples and the sintered PTFE materials are used as transfer standards for such calibrations because they have very stable reflectance factors that are nearly constant with wavelength and because the distribution of flux resembles closely that from the perfect reflecting diffuser.

    1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

    1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    E131 Terminology Relating to Molecular Spectroscopy

    E259 Practice for Preparation of Pressed Powder White Reflectance Factor Transfer Standards for Hemispherical and Bi-Directional Geometries

    E284 Terminology of Appearance

    ICS Code

    ICS Number Code 37.020 (Optical equipment)

    UNSPSC Code

    UNSPSC Code 41115406(Spectrophotometers)

    Referencing This Standard
    Link Here
    Link to Active (This link will always route to the current Active version of the standard.)

    DOI: 10.1520/E1791-96R21

    Citation Format

    ASTM E1791-96(2021), Standard Practice for Transfer Standards for Reflectance Factor for Near-Infrared Instruments Using Hemispherical Geometry, ASTM International, West Conshohocken, PA, 2021, www.astm.org

    Back to Top