ASTM D8091 - 16

    Standard Guide for Impregnation of Graphite with Molten Salt

    Active Standard ASTM D8091 | Developed by Subcommittee: D02.F0

    Book of Standards Volume: 05.05


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    Significance and Use

    5.1 The molten salt reactor is a nuclear reactor which uses graphite as reflector and structural material and fluoride molten salt as coolant. The graphite components will be submerged in the molten salt during the lifetime of the reactor. The porous structure of graphite may lead to molten salt permeation, which can affect the thermal and mechanical properties of graphite. Consequently, it is important to assess the effect of impregnation of molten salt on the properties of the as-manufactured graphite material.

    5.2 The purpose of this guide is to report considerations that should be included in the preparation of graphite samples representative of that after exposure to a molten salt environment. The degree to which the molten salt will infiltrate the graphite will depend upon a number of factors, including the type of graphite and the type and extent of porosity, the properties of the molten salt, the impregnation pressure and temperature, and the duration of the exposure of the graphite to the molten salt.

    5.3 The user of this guide will need to select impregnation parameters sufficiently representative of those in a molten salt reactor based on parameters provided by the designer. Alternatively, the user may select a standard set of impregnation conditions to allow comparisons across a range of graphites.

    5.4 This guide is not intended to be prescriptive. A typical apparatus and associated procedure is described. Some indication of the sensitivity of the procedure to graphite type and impregnation conditions is given in He, et al.3

    5.5 There are four major practical issues that must be addressed during the impregnation process:

    5.5.1 The density of molten salt is greater than that of graphite. A specially designed tool is required to submerge graphite samples in the molten salt during the impregnation process.

    5.5.2 Some molten salts (for example, FLiBe) are poisonous and it is therefore necessary to provide containment by performing procedures within a glove box.

    5.5.3 The graphite must be kept away from air to avoid oxidation at high temperature. This can be achieved by performing the impregnation process within a glove box with a controlled atmosphere.

    5.5.4 Pressure control of the molten salt can be difficult to achieve. A specially designed autoclave is needed to hold the sample and molten salt.

    5.6 In order to assess the quantity of molten salt in the graphite, parameter D is used as a variable in measuring the mechanical and thermal material properties. For a low impregnation pressure, the parameter Do is the ratio of salt volume to open pore volume. For a high impregnation pressure, the parameter Dt is the ratio of salt volume to total pore volume. The saturated value of Do can be greater than 1 when the molten salt impregnation takes place at high pressure. It is postulated that the internal microstructure of graphite has been damaged by the impregnation pressure and some closed pores have been opened. In this case, the parameter Dt is more appropriate to represent the impregnation process.

    1. Scope

    1.1 This guide covers procedures for the impregnation of graphite with molten salt under a consistent pressure and temperature. Such procedures are necessary if the user wishes to prepare graphite specimens for testing that have been exposed to a molten salt environment that may not necessarily represent material exposed to an operating reactor environment.

    1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this guide.

    1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.


    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    C559 Test Method for Bulk Density by Physical Measurements of Manufactured Carbon and Graphite Articles

    D7775 Guide for Measurements on Small Graphite Specimens


    ICS Code

    ICS Number Code 71.060.10 (Chemical elements)

    UNSPSC Code

    UNSPSC Code 11101507(Graphite)


    Referencing This Standard
    Link Here
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    DOI: 10.1520/D8091-16

    Citation Format

    ASTM D8091-16, Standard Guide for Impregnation of Graphite with Molten Salt, ASTM International, West Conshohocken, PA, 2016, www.astm.org

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