ASTM D7922 - 14

    Standard Test Method for Determination of Glycol for In-Service Engine Oils by Gas Chromatography

    Active Standard ASTM D7922 | Developed by Subcommittee: D02.04.0L

    Book of Standards Volume: 05.05

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    Significance and Use

    5.1 Some glycol/antifreeze dilution of in-service engine oil is normal under typical operating conditions. However, excessive glycol dilution can lead to decreased performance, premature wear, or sudden engine failure. This test method provides a means of quantifying the level of glycol based antifreeze dilution, allowing the user to take necessary action.

    1. Scope

    1.1 This test method covers the determination of glycol based antifreeze for in-service engine oil by derivative headspace/gas chromatography.

    1.2 Sample is derivatized in-situ directly in a headspace sampling vial prior to vapor phase extraction and injection into a gas chromatograph.

    1.3 The chemistry of the derivatization is unique to the detection of the molecules of ethylene glycol and 1,2-propylene glycol. 1,3-propylene glycol could also be detected but is not used in any known anti-freeze at this time. Other coolant analyses are beyond the scope of this test method.

    1.4 The derivatization process does not affect glycol breakdown products such as glycolate and formate and hence the presence of these compounds in the oil will not be quantified.

    1.5 The test method concentration range is from 50 µg/g to 1000 µg/g. Lower levels are possible by method modifications. Higher levels are possible through sample dilution.

    1.6 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D4291 Test Method for Trace Ethylene Glycol in Used Engine Oil

    E355 Practice for Gas Chromatography Terms and Relationships

    E594 Practice for Testing Flame Ionization Detectors Used in Gas or Supercritical Fluid Chromatography

    E1510 Practice for Installing Fused Silica Open Tubular Capillary Columns in Gas Chromatographs

    ICS Code

    ICS Number Code 75.100 (Lubricants, industrial oils and related products)

    UNSPSC Code

    UNSPSC Code 15121501(Engine oil); 15121807(Antifreeze)

    Referencing This Standard
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    DOI: 10.1520/D7922-14

    Citation Format

    ASTM D7922-14, Standard Test Method for Determination of Glycol for In-Service Engine Oils by Gas Chromatography, ASTM International, West Conshohocken, PA, 2014,

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