ASTM D7828 - 12

    Standard Test Method for Determination of Residue Composition in Liquefied Petroleum Gas (LPG) Using Automated Thermal Desorption/Gas Chromatography (ATD/GC)

    Active Standard ASTM D7828 | Developed by Subcommittee: D02.H0

    Book of Standards Volume: 05.05

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    Significance and Use

    5.1 Residue in LPG is a contaminant that can lead to operational problems in some end use applications. Engines, micro-turbines, fuel cells and other equipment may be sensitive to residue levels as low as 10 mg/kg.

    5.2 Contamination of LPG can occur during production, transport, delivery, storage and use. A qualitative indication of the contaminants can help track down the source of the contamination from manufacture, through the distribution system, and to the end user.

    5.3 This test method is designed to provide a lower detection limit, wider dynamic range, and better accuracy than gravimetric methods like Test Method D2158.

    5.4 This test method can be performed with little or no discharge of LPG vapors, compared to Test Method D2158 which requires evaporation of 100 mL of sample per test.

    5.5 Sampling for residue in LPG using sorbent tubes can be performed in the field, and the sorbent tubes sent to a laboratory for analysis. This saves significant costs in shipping (weight of tube is approximately 10 grams), and is much safer and easier than transporting LPG cylinders.

    5.6 This test method determines total residues from C6 to C40, compared to a thermal gravimetric residue method such as Test Method D2158 which heat the residue to 38°C, resulting in a lower recovery due to loss of lighter residue components.

    5.7 If there is a need to decrease the detection limit of residue or individual compounds of interest below 10 µg/g, the procedures in this test method can be modified to achieve 50 times enhanced detection limit, or 0.2 µg/g.

    1. Scope

    1.1 This test method covers the determination of residue in LPG by automated thermal desorption/gas chromatography (ATD/GC) using flame ionization detection (FID).

    1.2 The quantitation of residue covers a component boiling point range from 69°C to 522°C, equivalent to the boiling points of C6 through C40 n-paraffins.

    1.2.1 The boiling range covers possible LPG contaminants such as gasoline, diesel fuel, phthalates and compressor oil. Qualitative information on the nature of the residue can be obtained from this test method.

    1.2.2 Materials insoluble in LPG and components which do not elute from the gas chromatograph or which have no response in a flame ionization detector are not determined.

    1.2.3 The reporting limit (or limit of quantitation) for total residue is 6.7 µg/g.

    1.2.4 The dynamic range of residue quantitation is 6.7 to 3300 µg/g.

    1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D1265 Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method

    D1835 Specification for Liquefied Petroleum (LP) Gases

    D2158 Test Method for Residues in Liquefied Petroleum (LP) Gases

    D3700 Practice for Obtaining LPG Samples Using a Floating Piston Cylinder

    D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance

    E355 Practice for Gas Chromatography Terms and Relationships

    Environmental Protection Agency

    EPA Method TO-17 Determination of Volatile Organic Compounds in Ambient Air using Active Sampling onto Sorbent Tubes

    ICS Code

    ICS Number Code 75.160.30 (Gaseous fuels)

    UNSPSC Code

    UNSPSC Code 15111510(Liquified petroleum gas)

    Referencing This Standard
    Link Here
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    DOI: 10.1520/D7828-12

    Citation Format

    ASTM D7828-12, Standard Test Method for Determination of Residue Composition in Liquefied Petroleum Gas (LPG) Using Automated Thermal Desorption/Gas Chromatography (ATD/GC), ASTM International, West Conshohocken, PA, 2012,

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