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    ASTM D7806 - 20

    Standard Test Method for Determination of Biodiesel (Fatty Acid Methyl Ester) and Triglyceride Content in Diesel Fuel Oil Using Mid-Infrared Spectroscopy (FTIR Transmission Method)

    Active Standard ASTM D7806 | Developed by Subcommittee: D02.04.0F

    Book of Standards Volume: 05.04

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    Significance and Use

    5.1 Biodiesel is a fuel commodity primarily used as a value-added blending component with diesel fuel.

    5.2 This test method is applicable for quality control in the production and distribution of diesel fuel and biodiesel blends containing FAME.

    5.3 The use of triglycerides in fuels is not approved for transportation applications within any ASTM specification. This test method allows the quantification of triglyceride concentration in biodiesel blends, thus enabling detection of out-of-specification blending.

    5.4 This test method is fast, simple to run, inexpensive and requires no sample preparation.

    1. Scope

    1.1 This test method covers the determination of fatty acid methyl ester (FAME) biodiesel and triglyceride (TAG) concentrations in traditional diesel and renewable diesel fuel blends using a portable mid-infrared spectrometer.

    1.2 The method applies to samples with biodiesel concentrations from 3 % to 40 % by volume. Additionally, it applies to samples with biodiesel concentrations from 2 % to 27 % by volume which contain triglycerides concentrations from 1 % to 10 % by volume. Triglycerides from 2 % to 10 % by volume can be determined in samples of diesel having biodiesel concentrations from 3 % to 27 % by volume. FAME and triglyceride can be simultaneously determined outside these stated ranges, but the stated precision estimates do not apply.

    1.3 The method is not able to distinguish TAG and FAME if the TAG concentrations is below 0.142× the measured FAME concentrations.

    1.4 This procedure is not appropriate for the determination of the concentration of biodiesel in the form of fatty acid ethyl esters (FAEE), see Section 6 for further discussion of possible interferences.

    1.5 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

    1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

    1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D975 Specification for Diesel Fuel

    D1298 Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method

    D1655 Specification for Aviation Turbine Fuels

    D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter

    D4057 Practice for Manual Sampling of Petroleum and Petroleum Products

    D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products

    D4307 Practice for Preparation of Liquid Blends for Use as Analytical Standards

    D5854 Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products

    D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance

    D6300 Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants

    D6751 Specification for Biodiesel Fuel Blend Stock (B100) for Middle Distillate Fuels

    D7418 Practice for Set-Up and Operation of Fourier Transform Infrared (FT-IR) Spectrometers for In-Service Oil Condition Monitoring

    E131 Terminology Relating to Molecular Spectroscopy

    E168 Practices for General Techniques of Infrared Quantitative Analysis

    E1655 Practices for Infrared Multivariate Quantitative Analysis

    E2056 Practice for Qualifying Spectrometers and Spectrophotometers for Use in Multivariate Analyses, Calibrated Using Surrogate Mixtures

    ICS Code

    ICS Number Code 75.160.20 (Liquid fuels)

    UNSPSC Code

    UNSPSC Code 15101801(Biodiesel)

    Referencing This Standard
    Link Here
    Link to Active (This link will always route to the current Active version of the standard.)

    DOI: 10.1520/D7806-20

    Citation Format

    ASTM D7806-20, Standard Test Method for Determination of Biodiesel (Fatty Acid Methyl Ester) and Triglyceride Content in Diesel Fuel Oil Using Mid-Infrared Spectroscopy (FTIR Transmission Method), ASTM International, West Conshohocken, PA, 2020, www.astm.org

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