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    ASTM D7653 - 18

    Standard Test Method for Determination of Trace Gaseous Contaminants in Hydrogen Fuel by Fourier Transform Infrared (FTIR) Spectroscopy

    Active Standard ASTM D7653 | Developed by Subcommittee: D03.14

    Book of Standards Volume: 05.06

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    Significance and Use

    5.1 Fuel cell users have implicated trace impurities in feed gases as compromising the performance and lifespan of proton exchange membrane fuel cells (PEMFCs). PEMFCs may be damaged by the presence of some contaminants through poisoning of fuel cell electrode materials; therefore detection of these impurities at low concentrations is critical to fuel cell manufacturers and feed gas suppliers in order to support the facilities and infrastructure required for widespread applicability of fuel cells in transportation and energy production. With field-portable equipment, this test method can be used to quickly analyze hydrogen fuel for impurities at vehicle fueling stations or storage tanks used to supply stationary power plants. This test method can also be used by gas suppliers, customers, and regulatory agencies to certify hydrogen fuel quality.

    5.2 Users include hydrogen producers, gaseous fuel custody transfer stakeholders, fueling stations, fuel cell manufacturers, automotive manufacturers, regulators, and stationary fuel cell power plant operators.

    1. Scope

    1.1 This test method employs an FTIR gas analysis system for the determination of trace impurities in gaseous hydrogen fuels relative to the hydrogen fuel quality limits described in SAE TIR J2719 (April 2008) or in hydrogen fuel quality standards from other governing bodies. This FTIR method is used to quantify gas phase concentrations of multiple target contaminants in hydrogen fuel either directly at the fueling station or on an extracted sample that is sent to be analyzed elsewhere. Multiple contaminants can be measured simultaneously as long as they are in the gaseous phase and absorb in the infrared wavelength region. The detection limits as well as specific target contaminants for this standard were selected based upon those set forth in SAE TIR J2719.

    1.2 This test method allows the tester to determine which specific contaminants for hydrogen fuel impurities that are in the gaseous phase and are active infrared absorbers which meet or exceed the detection limits set by SAE TIR J2719 for their particular FTIR instrument. Specific target contaminants include, but are not limited to, ammonia, carbon monoxide, carbon dioxide, formaldehyde, formic acid, methane, ethane, ethylene, propane, and water. This test method may be extended to other impurities provided that they are in the gaseous phase or can be vaporized and are active infrared absorbers.

    1.3 This test method is intended for analysis of hydrogen fuels used for fuel cell feed gases or for internal combustion engine fuels. This method may also be extended to the analysis of high purity hydrogen gas used for other applications including industrial applications, provided that target impurities and required limits are also identified.

    1.4 This test method can be used to analyze hydrogen fuel sampled directly at the point-of-use from fueling station nozzles or other feed gas sources. The sampling apparatus includes a pressure regulator and metering valve to provide an appropriate gas stream for direct analysis by the FTIR spectrometer.

    1.5 This test method can also be used to analyze samples captured in storage vessels from point-of-use or other sources. Analysis of the stored samples can be performed either in a mobile laboratory near the sample source or in a standard analytical laboratory.

    1.6 A test plan should be prepared that includes (1) the specific impurity species to be measured, (2) the concentration limits for each impurity species, and (3) the determination of the minimum detectable concentration for each impurity species as measured on the apparatus before testing.

    1.7 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.7.1 Exception—All values are based upon common terms used in the industry of those particular values and when not consistent with SI units, the appropriate SI unit will be included in parentheses after the common value usage (4.4, 7.8, 7.9, 10.5, and 11.6).

    1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

    1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    EPA Documents

    EPA 40 CFR Protection of the Environment, Appendix Performance Specification for Extractive FTIR Continuous Emissions Monitoring Systems in Stationary Sources

    SAE Document

    SAE TIR J2719 Informational Report on the Development of a Hydrogen Quality Guideline for Fuel Cell Vehicles

    ASTM Standards

    D5287 Practice for Automatic Sampling of Gaseous Fuels

    D6348 Test Method for Determination of Gaseous Compounds by Extractive Direct Interface Fourier Transform Infrared (FTIR) Spectroscopy

    D7606 Practice for Sampling of High Pressure Hydrogen and Related Fuel Cell Feed Gases

    ICS Code

    ICS Number Code 71.100.20 (Gases for industrial application)

    UNSPSC Code

    UNSPSC Code 15111500(Gaseous fuels)

    Referencing This Standard
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    DOI: 10.1520/D7653-18

    Citation Format

    ASTM D7653-18, Standard Test Method for Determination of Trace Gaseous Contaminants in Hydrogen Fuel by Fourier Transform Infrared (FTIR) Spectroscopy, ASTM International, West Conshohocken, PA, 2018, www.astm.org

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