ASTM D7573 - 18

    Standard Test Method for Total Carbon and Organic Carbon in Water by High Temperature Catalytic Combustion and Infrared Detection

    Active Standard ASTM D7573 | Developed by Subcommittee: D19.06

    Book of Standards Volume: 11.02


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    Significance and Use

    5.1 This test method is used for determination of the carbon content of water from a variety of natural, domestic, and industrial sources. In its most common form, this test method is used to measure organic carbon as a means of monitoring organic pollutants in industrial wastewater. These measurements are also used in monitoring waste treatment processes.

    5.2 The relationship of TOC to other water quality parameters such as chemical oxygen demand (COD) and total oxygen demand (TOD) is described in the literature.4

    1. Scope

    1.1 This test method covers the determination of total carbon (TC), inorganic carbon (IC), total organic carbon (TOC), dissolved organic carbon (DOC), and non-purgable organic carbon (NPOC) in drinking water, groundwater, surface water, wastewater, and seawater in the range from 0.5 mg/L to 50 mg/L. Concentrations of 50–4000 mg/L of carbon may be determined by automated injection of less sample volume or by sample dilution. Alternatively, use less sample volume and calibrate at higher concentrations..

    1.2 The sample is injected into a tube heated at 680ºC. The sample converts into a gaseous phase and forced through a layer of catalyst ensuring conversion of all carbon containing compounds to CO2. A non-dispersive infrared (NDIR) detector measures the resulting CO2.

    1.3 For TOC and DOC analysis a portion of the sample is injected to determine TC or dissolved carbon (DC). A portion of the sample is then acidified and purged to remove the IC. The purged inorganic carbon is measured as TIC, or DIC. TOC or DOC is calculated by subtracting the inorganic fraction from the total carbon:

    Equation D7573-18_1

    1.4 For NPOC analysis a portion of sample is acidified and purged to remove IC. The purged sample is then injected to determine NPOC.

    1.5 This test method is applicable to the matrices and concentrations validated in the inter-laboratory study. It is the user's responsibility to ensure the validity of this test method for waters of untested matrices and different concentration ranges.

    1.6 This test method is applicable only to carbonaceous matter in the sample that can be introduced into the reaction zone. The syringe needle or injector opening size generally limits the maximum size of particles that can be so introduced.

    1.7 In addition to laboratory analyses, this test method may be applied to stream monitoring.

    1.8 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

    1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D1129 Terminology Relating to Water

    D1192 Guide for Equipment for Sampling Water and Steam in Closed Conduits

    D1193 Specification for Reagent Water

    D2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

    D3370 Practices for Sampling Water from Closed Conduits

    D4448 Guide for Sampling Ground-Water Monitoring Wells

    D5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

    D6538 Guide for Sampling Wastewater With Automatic Samplers

    D6759 Practice for Sampling Liquids Using Grab and Discrete Depth Samplers


    ICS Code

    ICS Number Code 13.060.50 (Examination of water for chemical substances)

    UNSPSC Code

    UNSPSC Code


    Referencing This Standard
    Link Here
    Link to Active (This link will always route to the current Active version of the standard.)

    DOI: 10.1520/D7573-18

    Citation Format

    ASTM D7573-18, Standard Test Method for Total Carbon and Organic Carbon in Water by High Temperature Catalytic Combustion and Infrared Detection, ASTM International, West Conshohocken, PA, 2018, www.astm.org

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