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Significance and Use
5.1 Hydrogen cyanide is highly toxic. In relatively low quantities, hydrogen cyanide can cause asphyxia and death.
5.2 The National Fire Protection Association has assigned a flammability rating of 4 (severe fire hazard) to hydrogen cyanide.
1.1 This practice is used to collect samples for the determination of gaseous hydrogen cyanide (HCN) from any combustion device or atmosphere where cyanide may be present. While primarily designed for the measurement of gas phase HCN, the sample collection described in this practice also includes cyanide ion (CN-) absorbed particles that may be present in the sampling atmosphere.
1.1.1 Samples can be collected from a closed chamber such as the NBS smoke box described in Test Method provided it is equipped with sampling ports.
1.1.2 Open chambers such as industrial work areas or large scale fires can be monitored for HCN with this practice.
1.1.3 The HCN emissions of a flow through system can be determined by sampling from its discharge stack. Examples of such systems include large scale manufacturing applications and the cone calorimeter described in Test Method .
1.2 This practice can be used to monitor HCN levels in lab scale fire smoke effluents in order to estimate toxicity of gases produced from burning materials. See Guide .
1.3 The concentration range of hydrogen cyanide will be dependent on the volume of gas sampled, the volume of sodium hydroxide solution placed in the impinger during sampling, and the analytical method used to measure cyanide. For example, the lower limit of detection would be 0.002-mg/m3 when 0.1-m3 of combustion effluent is collected into 100-mL sodium hydroxide solution based on a detection limit of 0.002 mg/L cyanide in the impinger solution when using the flow injection analysis (FIA) system described in Test Method .
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D1193 Specification for Reagent Water
D1356 Terminology Relating to Sampling and Analysis of Atmospheres
D2036 Test Methods for Cyanides in Water
D2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
D3154 Test Method for Average Velocity in a Duct (Pitot Tube Method)
D3614 Guide for Laboratories Engaged in Sampling and Analysis of Atmospheres and Emissions
D3685/D3685M Test Methods for Sampling and Determination of Particulate Matter in Stack Gases
D4841 Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents
D5337 Practice for Flow Rate Adjustment of Personal Sampling Pumps
D6696 Guide for Understanding Cyanide Species
D6888 Test Method for Available Cyanides with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
D7365 Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
E337 Test Method for Measuring Humidity with a Psychrometer (the Measurement of Wet- and Dry-Bulb Temperatures)
E662 Test Method for Specific Optical Density of Smoke Generated by Solid Materials
E800 Guide for Measurement of Gases Present or Generated During Fires
E1354 Test Method for Heat and Visible Smoke Release Rates for Materials and Products Using an Oxygen Consumption Calorimeter
E2877 Guide for Digital Contact Thermometers
ICS Number Code 13.040.40 (Stationary source emissions)
UNSPSC Code 77121501(Air quality management)
|Link to Active (This link will always route to the current Active version of the standard.)|
ASTM D7295-18, Standard Practice for Sampling Combustion Effluents and Other Stationary Sources for the Subsequent Determination of Hydrogen Cyanide, ASTM International, West Conshohocken, PA, 2018, www.astm.orgBack to Top