| ||Format||Pages||Price|| |
|27||$78.00||  ADD TO CART|
|Hardcopy (shipping and handling)||27||$78.00||  ADD TO CART|
|Standard + Redline PDF Bundle||54||$92.00||  ADD TO CART|
Significance and Use
5.1 This method directly determines the concentration of metal cyanide complexes in environmental waters. The method is important from an environmental regulatory perspective because it differentiates metal cyanide complexes of lesser toxicity from metal cyanide complexes of greater toxicity. Previous determinations of strong metal cyanide complexes assumed that the concentration of strong metal cyanide complexes is equivalent to the difference between the total cyanide and the free cyanide. This approach is subject to error because different methods used to determine free cyanide often provide widely varying results, thus impacting the strong metal cyanide complex concentration that is determined by difference. The direct analysis using anion exchange chromatography avoids these method biases and provides for a more accurate and precise determination of metal cyanide complexes.
1.1 This test method covers the determination of the metal cyanide complexes of iron, cobalt, silver, gold, copper and nickel in waters including groundwaters, surface waters, drinking waters and wastewaters by anion exchange chromatography and UV detection. The use of alkaline sample preservation conditions (see ) ensures that all metal cyanide complexes are solubilized and recovered in the analysis (. )
1.2 Metal cyanide complex concentrations between 0.20 to 200 mg/L may be determined by direct injection of the sample. This range will differ depending on the specific metal cyanide complex analyte, with some exhibiting greater or lesser detection sensitivity than others. Approximate concentration ranges are provided in . Concentrations greater than the specific analyte range may be determined after appropriate dilution. This test method is not applicable for matrices with high ionic strength (conductivity greater than 500 meq/L as Cl) and TDS (greater than 30 000 mg/L), such as ocean water.
1.3 Metal cyanide complex concentrations less than 0.200 mg/L may be determined by on-line sample preconcentration coupled with anion exchange chromatography as described in . This range will differ depending on the specific metal cyanide complex analyte, with some exhibiting greater or lesser detection sensitivity than others. Approximate concentration ranges are provided in . The preconcentration method is not applicable for silver and copper cyanide complexes in matrices with high TDS (greater than 1000 mg/L).
1.4 The test method may also be applied to the determination of additional metal cyanide complexes, such as those of platinum and palladium. However, it is the responsibility of the user of this standard to establish the validity of the test method for the determination of cyanide complexes of metals other than those in .
1.5 The presence of metal complexes within a sample may be converted to Metal CN complexes and as such, are altered with the use of this method. This method is not applicable to samples that contain anionic complexes of metals that are weaker than cyanide complexes of those metals.
1.6 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, refer to Section .
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D1129 Terminology Relating to Water
D1193 Specification for Reagent Water
D2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
D3370 Practices for Sampling Water from Closed Conduits
D3856 Guide for Management Systems in Laboratories Engaged in Analysis of Water
D5810 Guide for Spiking into Aqueous Samples
D5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
D6696 Guide for Understanding Cyanide Species
ICS Number Code 13.060.50 (Examination of water for chemical substances)
UNSPSC Code 12352117(Cyanides or isocyanides)
|Link to Active (This link will always route to the current Active version of the standard.)|
ASTM D6994-15, Standard Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection, ASTM International, West Conshohocken, PA, 2015, www.astm.orgBack to Top