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    ASTM D6173 - 97(2014)

    Standard Test Method for Determination of Various Anionic Surfactant Actives by Potentiometric Titration

    Active Standard ASTM D6173 | Developed by Subcommittee: D12.12

    Book of Standards Volume: 15.04

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    Significance and Use

    5.1 The most common anionic surfactants presented in this test method are used widely in synthetic detergents and other household cleaners. Current analysis of the active matter in these anionic surfactants involves the two-phase aqueous/chloroform titration with a mixed indicator, organic dyes such as disulphine blue/dimidium bromide (see Test Method D3049), and methylene blue (see Test Method D1681). This test method eliminates the use of hazardous chloroform, the use of which is restricted for environmental and toxicological reasons.

    5.2 This test method also describes the titration of various ratio blends of sodium alkylbenzene sulfonate and sodium xylene sulfonate. Active matter content in these blends is attributable directly to sodium alkylbenzene sulfonate. Therefore, the presence of various amounts of sodium xylene sulfonate in these blends does not interfere with the determination of percent actives.

    1. Scope

    1.1 This test method is based on a potentiometric titration of common anionic surfactants and blends of anionic surfactant with a hydrotrope. This test method solely is intended for the analysis of active matter in the following surfactants: alcohol ether sulfate, alpha olefin sulfonate, alkylbenzene sulfonic acid, alcohol sulfate, sodium alkylbenzene sulfonate/sodium xylene sulfonate blend (5:1), sodium alkylbenzene sulfonate/sodium xylene sulfonate blend (16:1), and sodium alkylbenzene sulfonate/sodium xylene sulfonate blend (22:1). It has not been tested for surfactant formulations.

    1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.3 This standard does not purport to address all the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Material Safety Data Sheets are available for reagents and materials. Review them for hazards prior to usage.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D459 Terminology Relating to Soaps and Other Detergents

    D1681 Test Method for Synthetic Anionic Active Ingredient in Detergents by Cationic Titration Procedure

    D3049 Test Method for Synthetic Anionic Ingredient by Cationic Titration

    ICS Code

    ICS Number Code 71.040.99 (Other standards related to analytical chemistry)

    UNSPSC Code

    UNSPSC Code 12161902(Detergent surfactants)

    Referencing This Standard
    Link Here
    Link to Active (This link will always route to the current Active version of the standard.)

    DOI: 10.1520/D6173-97R14

    Citation Format

    ASTM D6173-97(2014), Standard Test Method for Determination of Various Anionic Surfactant Actives by Potentiometric Titration, ASTM International, West Conshohocken, PA, 2014, www.astm.org

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