ASTM D6133 - 02(2014)
Standard Test Method for Acetone, p-Chlorobenzotrifluoride, Methyl Acetate or t-Butyl Acetate Content of Solventborne and Waterborne Paints, Coatings, Resins, and Raw Materials by Direct Injection Into a Gas Chromatograph
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Significance and Use
4.1 With the need to calculate volatile organic content (VOC) of paints, and with acetone, p-chlorobenzotrifluoride, methyl acetate and t-butyl acetate4 considered as exempt volatile compounds, it is necessary to know the content of these analytes. This gas chromatographic test method provides a relatively simple and direct way to determine their content. However, because the detectors used in this test method are not selective, and because some coatings are very complex mixtures, compounds may be present in the sample that coelute with the analyte, giving a result that is erroneously high. Or a component may elute with the internal standard, giving a result that is erroneously low. It is therefore important to know the composition of the sample to ensure that there are no interferences, under the analysis conditions used. Test Method D6438 employs mass-spectral detection of analytes and may be used as an alternative method.
1. Scope
1.1 This test method is for the determination of the total-concentration of acetone, p-chlorobenzotrifluoride, methyl acetate, or t-butyl acetate, or combination of any of the four, in solvent-reducible and water-reducible paints, coatings, resins, and raw materials. Because unknown compounds that co-elute with the analyte being measured or with the internal standard, will lead to erroneous results, this test method should only be used for materials of known composition so that the possibility of interferences can be eliminated. The established working range of this test method is from 1 % to 100 % for each analyte by weight.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
ASTM Standards
D3271 Practice for Direct Injection of Solvent-Reducible Paints Into a Gas Chromatograph for Solvent Analysis
D3272 Practice for Vacuum Distillation of Solvents From Solvent-Reducible Paints For Analysis
D6438 Test Method for Acetone, Methyl Acetate, and Parachlorobenzotrifluoride Content of Paints, and Coatings by Solid Phase Microextraction-Gas Chromatography
E177 Practice for Use of the Terms Precision and Bias in ASTM Test Methods
E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
ICS Code
ICS Number Code 87.040 (Paints and varnishes); 87.060.01 (Paint ingredients in general)
UNSPSC Code
UNSPSC Code 31211502(Water based paints)
Referencing This Standard
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DOI: 10.1520/D6133-02R14
Citation Format
ASTM D6133-02(2014), Standard Test Method for Acetone, p-Chlorobenzotrifluoride, Methyl Acetate or t-Butyl Acetate Content of Solventborne and Waterborne Paints, Coatings, Resins, and Raw Materials by Direct Injection Into a Gas Chromatograph, ASTM International, West Conshohocken, PA, 2014, www.astm.org
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