ASTM D5575 - 07(2013)

    Standard Classification System for Copolymers of Vinylidene Fluoride (VDF) with Other Fluorinated Monomers

    Active Standard ASTM D5575 | Developed by Subcommittee: D20.15

    Book of Standards Volume: 08.03

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    This classification system covers both developing property designations and specifications for thermoplastic compositions consisting of vinylidene fluoride (VDF) polymers modified with other fluoromonomers and property-enhancing additives. Four property codes are presented: code 1 - melt temperature, code 2 - melt-flow rate or melt viscosity, or both, code 3 - tensile strength and modulus, and code 5 - density. The melt temperatures, melt-flow rate, melt viscosity, tensile properties, specific gravity, volume resistivity, dielectric constant, dissipation factor, and limiting oxygen index shall be tested to meet the requirements prescribed.

    This abstract is a brief summary of the referenced standard. It is informational only and not an official part of the standard; the full text of the standard itself must be referred to for its use and application. ASTM does not give any warranty express or implied or make any representation that the contents of this abstract are accurate, complete or up to date.

    1. Scope

    1.1 This classification system covers both developing property designations and specifications for thermoplastic compositions consisting of vinylidene fluoride (VDF) polymers modified with other fluoromonomers and property-enhancing additives. The other fluoromonomers include one or more of the following: hexafluoropropylene (HFP), tetrafluoroethylene (TFE), and chlorotrifluoroethylene (CTFE). The additives are those that improve its flame resistance, processing, or physical properties. However, these additives are not normally considered to be reinforcing. This classification system covers thermoplastic compositions supplied in pellet or powder forms.

    1.2 A designation or specification applies only to the virgin polymers prepared from vinylidene fluoride (>50 weight %) with one or more of the following comonomers: hexafluoropropylene, tetrafluoroethylene, and chlorotrifluoroethylene. Some polymers contain additives to enhance certain properties.

    1.3 This system constitutes a line callout as a means of designating and specifying properties of VDF-based copolymers. At least four of the designated properties are used to define a polymer's specification. Specification criteria from international documents can be used if their criteria match designation properties currently used by this classification system.2 This classification system is not intended for the selection of materials.

    1.4 The manufacturer of the virgin resin shall establish the designation of a resin based on the property value criteria in this classification system.

    1.5 The minimum specification properties are established by this classification system. Additional specification properties, based on the designation properties cited, can be established by the resin supplier and customer.

    1.6 The values stated in SI units are to be regarded as standard.

    1.7 The property tests are intended to provide information for specifications of modified VDF-copolymer compositions. It is not the purpose of this classification system to provide engineering data for design purposes.

    Note 1Although the values listed in Table 1, Table 2, Table 3, Table 4, and Table are necessary to include the range of properties available in existing materials, they are not to be interpreted as implying that every possible combination of the properties exists or can be obtained. It is possible for a user or designer, using Tables 1-, to call out property relationships that are physically impossible to occur in a copolymer made using current technology.
    Note 2Many of these polymers exhibit polymorphism.3 The type and extent of crystalline structure will vary with the thermomechanical history of the sample. Properties vary based on the technique used to prepare the specimens.

    1.8 Test methods used in this classification system can result in the incidental production of hazardous materials. Modified VDF polymer fluoroplastics melt between 90 and 182°C (194 and 359°F) and are thermally stable up to about 350°C (662°F), or somewhat higher, depending on the composition. (Warning— Evolution of corrosive, colorless, and toxic hydrogen fluoride can occur under certain conditions.)

    1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. See Warning in 1.8 and Section 10 for specific hazards statements.

    Note 3Many, but not all of the codes and specifications found in this classification system are also in ISO 12086-1 and ISO 12086-2.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D150 Test Methods for AC Loss Characteristics and Permittivity (Dielectric Constant) of Solid Electrical Insulation

    D257 Test Methods for DC Resistance or Conductance of Insulating Materials

    D618 Practice for Conditioning Plastics for Testing

    D638 Test Method for Tensile Properties of Plastics

    D792 Test Methods for Density and Specific Gravity (Relative Density) of Plastics by Displacement

    D883 Terminology Relating to Plastics

    D1238 Test Method for Melt Flow Rates of Thermoplastics by Extrusion Plastometer

    D1600 Terminology for Abbreviated Terms Relating to Plastics

    D2863 Test Method for Measuring the Minimum Oxygen Concentration to Support Candle-Like Combustion of Plastics (Oxygen Index)

    D3222 Specification for Unmodified Poly(Vinylidene Fluoride) (PVDF) Molding Extrusion and Coating Materials

    D3418 Test Method for Transition Temperatures and Enthalpies of Fusion and Crystallization of Polymers by Differential Scanning Calorimetry

    D3835 Test Method for Determination of Properties of Polymeric Materials by Means of a Capillary Rheometer

    D3892 Practice for Packaging/Packing of Plastics

    D4591 Test Method for Determining Temperatures and Heats of Transitions of Fluoropolymers by Differential Scanning Calorimetry

    D4703 Practice for Compression Molding Thermoplastic Materials into Test Specimens, Plaques, or Sheets

    D5740 Guide for Writing Material Standards in the Classification Format

    ICS Code

    ICS Number Code 83.080.20 (Thermoplastic materials)

    UNSPSC Code

    UNSPSC Code 13111074(Polyvinylidene Fluoride)

    Referencing This Standard
    Link Here
    Link to Active (This link will always route to the current Active version of the standard.)

    DOI: 10.1520/D5575

    Citation Format

    ASTM D5575-07(2013), Standard Classification System for Copolymers of Vinylidene Fluoride (VDF) with Other Fluorinated Monomers, ASTM International, West Conshohocken, PA, 2013,

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