Standard Active Last Updated: Dec 08, 2022 Track Document
ASTM D5128-14(2022)

Standard Test Method for On-Line pH Measurement of Water of Low Conductivity

Standard Test Method for On-Line pH Measurement of Water of Low Conductivity D5128-14R22 ASTM|D5128-14R22|en-US Standard Test Method for On-Line pH Measurement of Water of Low Conductivity Standard new BOS Vol. 11.01 Committee D19
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Significance and Use

5.1 Continuous pH measurements in low conductivity samples are sometimes required in pure water treatment using multiple pass reverse osmosis processes. Membrane rejection efficiency for several contaminants depends on pH measurement and control between passes where the conductivity is low.

5.2 Continuous pH measurement is used to monitor power plant cycle chemistry where small amounts of ammonia or amines or both are added to minimize corrosion by high temperature pure water and steam.

5.3 Conventional pH measurements are made in solutions that contain relatively large amounts of acid, base, or dissolved salts. Under these conditions, pH determinations may be made quickly and precisely. Continuous on-line pH measurements in water samples of low conductivity are more difficult (4, 5). These low ionic strength solutions are susceptible to contamination from the atmosphere, sample stream hardware, and the pH electrodes. Variations in the constituent concentration of low conductivity waters cause liquid junction potential shifts (see 3.2.1) resulting in pH measurement errors. Special precautions are required.

Scope

1.1 This test method covers the precise on-line determination of pH in water samples of conductivity lower than 100 μS/cm (see Table 1 and Table 2) over the pH range of 3 to 11 (see Fig. 1), under field operating conditions. pH measurements of water of low conductivity are problematic for conventional pH electrodes, methods, and related measurement apparatus.

FIG. 1 Restrictions Imposed by the Conductivity pH Relationship

 Restrictions Imposed by the Conductivity pH Relationship Restrictions Imposed by the Conductivity pH Relationship

1.2 This test method includes the procedures and equipment required for the continuous pH measurement of low conductivity water sample streams including the requirements for the control of sample stream pressure, flow rate, and temperature. For off-line pH measurements in low conductivity samples, refer to Test Method D5464.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Details
Book of Standards Volume: 11.01
Developed by Subcommittee: D19.03
Pages: 11
DOI: 10.1520/D5128-14R22
ICS Code: 71.040.50