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Significance and Use
5.1 Ethers, alcohols, and other oxygenates can be added to gasoline to increase octane number and to reduce emissions. Type and concentration of various oxygenates are specified and regulated to ensure acceptable commercial gasoline quality. Drivability, vapor pressure, phase separation, exhaust, and evaporative emissions are some of the concerns associated with oxygenated fuels.
5.2 This test method is applicable to both quality control in the production of gasoline and for the determination of deliberate or extraneous oxygenate additions or contamination.
1.1 This test method covers the determination of ethers and alcohols in gasolines by gas chromatography. Specific compounds determined are methyl tert-butylether (MTBE), ethyl tert-butylether (ETBE), tert-amylmethylether (TAME), diisopropylether (DIPE), methanol, ethanol, isopropanol, n-propanol, isobutanol, tert-butanol, sec -butanol, n-butanol, and tert-pentanol (tert-amylalcohol).
1.2 Individual ethers are determined from 0.20 mass % to 20.0 mass %. Individual alcohols are determined from 0.20 mass % to 12.0 mass %. Equations used to convert to mass % oxygen and to volume % of individual compounds are provided. At concentrations <0.20 mass %, it is possible that hydrocarbons may interfere with several ethers and alcohols. The reporting limit of 0.20 mass % was tested for gasolines containing a maximum of 10 volume % olefins. It may be possible that for gasolines containing >10 volume % olefins, the interference may be >0.20 mass %. gives a chromatogram showing the interference observed with a gasoline containing 10 volume % olefins.
1.3 This test method includes a relative bias correlation for ethanol in spark-ignition engine fuels for the U.S. EPA regulations reporting based on Practice accuracy assessment between Test Method and Test Method as a possible Test Method alternative to Test Method . The Practice derived correlation equation is only applicable for ethanol in fuels in the concentration range from 2.28 % to 14.42 % by mass as measured by Test Method . The applicable Test Method range for ethanol is from 2.16 % to14.39 % by mass as reported by Test Method .
1.4 Alcohol-based fuels, such as M-85 and E-85, MTBE product, ethanol product, and denatured alcohol, are specifically excluded from this test method. The methanol content of M-85 fuel is considered beyond the operating range of the system.
1.5 Benzene, while detected, cannot be quantified using this test method and must be analyzed by alternate methodology (see Test Method ).
1.6 The values stated in SI units are to be regarded as standard. Alternate units, in common usage, are also provided to increase clarity and aid the users of this test method.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D1298 Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
D1744 Test Method for Water in Liquid Petroleum Products by Karl Fischer Reagent3
D3606 Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4307 Practice for Preparation of Liquid Blends for Use as Analytical Standards
D4420 Test Method for Determination of Aromatics in Finished Gasoline by Gas Chromatography
D5599 Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection
D6708 Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ICS Number Code 75.160.20 (Liquid fuels)
|Link to Active (This link will always route to the current Active version of the standard.)|
ASTM D4815-15b, Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C