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    ASTM D4628 - 16

    Standard Test Method for Analysis of Barium, Calcium, Magnesium, and Zinc in Unused Lubricating Oils by Atomic Absorption Spectrometry

    Active Standard ASTM D4628 | Developed by Subcommittee: D02.03

    Book of Standards Volume: 05.02

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    Significance and Use

    4.1 Some oils are formulated with metal-containing additives that act as detergents, antioxidants, antiwear agents, etc. Some of these additives contain one or more of these metals: barium, calcium, zinc, and magnesium. This test method provides a means of determining the concentration of these metals that gives an indication of the additive content in these oils.

    4.2 Several additive metals and their compounds are added to the lubricating oils to give beneficial performance. (See Table 1.)

    1. Scope

    1.1 This test method is applicable for the determination of mass percent barium from 0.005 % to 1.0 %, calcium and magnesium from 0.002 % to 0.3 %, and zinc from 0.002 % to 0.2 % in lubricating oils.

    1.2 Higher concentrations can be determined by appropriate dilution. Lower concentrations of metals such as barium, calcium, magnesium, and zinc at about 10 ppm level can also be determined by this test method. Use of this test method for the determination at these lower concentrations should be by agreement between the buyer and the seller.

    1.3 Lubricating oils that contain viscosity index improvers may give low results when calibrations are performed using standards that do not contain viscosity index improvers.

    1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific warning statements are given in 3.1, 6.3, and 8.1.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance

    ICS Code

    ICS Number Code 71.040.50 (Physicochemical methods of analysis); 75.100 (Lubricants, industrial oils and related products)

    Referencing This Standard
    Link Here
    Link to Active (This link will always route to the current Active version of the standard.)

    DOI: 10.1520/D4628-16

    Citation Format

    ASTM D4628-16, Standard Test Method for Analysis of Barium, Calcium, Magnesium, and Zinc in Unused Lubricating Oils by Atomic Absorption Spectrometry, ASTM International, West Conshohocken, PA, 2016, www.astm.org

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