ASTM D4463 / D4463M - 19

    Standard Guide for Metals Free Steam Deactivation of Fresh Fluid Cracking Catalysts

    Active Standard ASTM D4463 / D4463M | Developed by Subcommittee: D32.04

    Book of Standards Volume: 05.06

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    Significance and Use

    4.1 In general, steam treatment of FCC catalyst can be used either to compare a series of cracking catalysts at a simulated equilibrium condition or conditions, or to simulate the equilibrium condition of a specific cracking unit and a specific catalyst. This guide gives an example for the first purpose and an approach for the latter purpose.

    1. Scope

    1.1 This guide covers the deactivation of fresh fluid catalytic cracking (FCC) catalyst by hydrothermal treatment prior to the determination of the catalytic cracking activity in the microactivity test (MAT) or the Advanced Cracking Evaluation (ACE) test.

    1.2 The hydrothermal treatment of fresh FCC catalyst, prior to the MAT or the ACE test, is important because the catalytic activity of the catalyst in its fresh state is an inadequate measure of its true commercial performance. During operation in a commercial cracking unit, the catalyst is deactivated by thermal, hydrothermal, and chemical degradation. Therefore, to maintain catalytic activity, fresh catalyst is added (semi) continuously to the cracking unit, to replace catalyst lost through the stack or by withdrawal, or both. Under steady state conditions, the catalyst inventory of the unit is called equilibrium catalyst. This catalyst has an activity level substantially below that of fresh catalyst. Therefore, artificially deactivating a fresh catalyst prior to determination of its cracking activity should provide more meaningful catalyst performance data.

    1.3 Due to the large variations in properties among fresh FCC catalyst types as well as between commercial cracking unit designs or operating conditions, or both, no single set of steam deactivation conditions is adequate to artificially simulate the equilibrium catalyst for all purposes.

    1.3.1 In addition, there are many other factors that will influence the properties and performance of the equilibrium catalyst. These include, but are not limited to: deposition of heavy metals such as Ni, V, and Cu; deposition of light metals such as Na; and contamination from attrited refractory linings of vessel walls. Furthermore, commercially derived equilibrium catalyst represents a distribution of catalysts of different ages (from fresh to >300 days). Despite these apparent problems, it is possible to obtain reasonably close agreement between the performances of steam deactivated and equilibrium catalysts. It is also recognized that it is possible to steam deactivate a catalyst so that its properties and performance poorly represent the equilibrium. It is therefore recommended that when assessing the performance of different catalyst types, a common steaming condition be used. Catalyst deactivation by metals deposition is not addressed in this guide, but is addressed in Guide D7206/D7206M.

    1.4 This guide offers two approaches to steam deactivate fresh catalysts. The first part provides specific sets of conditions (time, temperature, and steam pressure) that can be used as general pre-treatments prior to comparison of fresh FCC catalyst MAT activities (Test Method D3907) or activities plus selectivities (Test Methods D5154 and D7964).

    1.4.1 The second part provides guidance on how to pretreat catalysts to simulate their deactivation in a specific FCCU and suggests catalyst properties which can be used to judge adequacy of the simulation. This technique is especially useful when examining how different types of catalyst may perform in a specific FCCU, provided no other changes (catalyst addition rate, regenerator temperature, contaminant metals levels, etc.) occur. This approach covers catalyst physical properties that can be used as monitors to indicate the closeness to equilibrium catalyst properties.

    1.5 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.

    1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

    1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D3663 Test Method for Surface Area of Catalysts and Catalyst Carriers

    D3907 Test Method for Testing Fluid Catalytic Cracking (FCC) Catalysts by Microactivity Test

    D3942 Test Method for Determination of the Unit Cell Dimension of a Faujasite-Type Zeolite

    D4365 Test Method for Determining Micropore Volume and Zeolite Area of a Catalyst

    D5154 Test Method for Determining Activity and Selectivity of Fluid Catalytic Cracking (FCC) Catalysts by Microactivity Test

    D7206/D7206M Guide for Cyclic Deactivation of Fluid Catalytic Cracking (FCC) Catalysts with Metals

    D7964 Test Method for Determining Activity of Fluid Catalytic Cracking (FCC) Catalysts in a Fluidized Bed

    E105 Practice for Probability Sampling of Materials

    E177 Practice for Use of the Terms Precision and Bias in ASTM Test Methods

    E456 Terminology Relating to Quality and Statistics

    E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method

    ICS Code

    ICS Number Code 71.040.30 (Chemical reagents)

    UNSPSC Code

    UNSPSC Code

    Referencing This Standard
    Link Here
    Link to Active (This link will always route to the current Active version of the standard.)

    DOI: 10.1520/D4463_D4463M-19

    Citation Format

    ASTM D4463 / D4463M-19, Standard Guide for Metals Free Steam Deactivation of Fresh Fluid Cracking Catalysts, ASTM International, West Conshohocken, PA, 2019,

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