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Significance and Use
5.1 The bromine number is useful as a measure of aliphatic unsaturation in petroleum samples. When used in conjunction with the calculation procedure described in , it can be used to estimate the percentage of olefins in petroleum distillates boiling up to approximately 315 °C (600 °F).
5.2 The bromine number of commercial aliphatic monoolefins provides supporting evidence of their purity and identity.
1.1 This test method covers the determination of the bromine number of the following materials:
1.1.1 Petroleum distillates that are substantially free of material lighter than isobutane and that have 90 % distillation points (by Test Method ) under 327 °C (626 °F). This test method is generally applicable to gasoline (including leaded, unleaded, and oxygenated fuels), kerosine, and distillates in the gas oil range that fall in the following limits:
90 % Distillation Point, °C (°F)
Bromine Number, max
Under 205 (400)
205 to 327 (400 to 626)
1.1.2 Commercial olefins that are essentially mixtures of aliphatic mono-olefins and that fall within the range of 95 to 165 bromine number (see ). This test method has been found suitable for such materials as commercial propylene trimer and tetramer, butene dimer, and mixed nonenes, octenes, and heptenes. This test method is not satisfactory for normal alpha-olefins.
Note 1: These limits are imposed since the precision of this test method has been determined only up to or within the range of these bromine numbers.
1.2 The magnitude of the bromine number is an indication of the quantity of bromine-reactive constituents, not an identification of constituents; therefore, its application as a measure of olefinic unsaturation should not be undertaken without the study given in .
1.3 For petroleum hydrocarbon mixtures of bromine number less than 1.0, a more precise measure for bromine-reactive constituents can be obtained by using Test Method . If the bromine number is less than 0.5, then Test Method or the comparable bromine index methods for industrial aromatic hydrocarbons, Test Methods or must be used in accordance with their respective scopes. The practice of using a factor of 1000 to convert bromine number to bromine index is not applicable for these lower values of bromine number.
1.4 The values stated in SI units are to be regarded as the standard.
1.4.1 Exception—The values given in parentheses are for information only.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Sections . , , and
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D86 Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure
D1193 Specification for Reagent Water
D1492 Test Method for Bromine Index of Aromatic Hydrocarbons by Coulometric Titration
D2710 Test Method for Bromine Index of Petroleum Hydrocarbons by Electrometric Titration
D5776 Test Method for Bromine Index of Aromatic Hydrocarbons by Electrometric Titration
ICS Number Code 75.080 (Petroleum products in general); 75.100 (Lubricants, industrial oils and related products)
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ASTM D1159-07(2017), Standard Test Method for Bromine Numbers of Petroleum Distillates and Commercial Aliphatic Olefins by Electrometric Titration, ASTM International, West Conshohocken, PA, 2017, www.astm.orgBack to Top