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Significance and Use
4.1 Iron is the second most abundant metallic element in the earth's crust and is essential in the metabolism of plants and animals. If presented in excessive amounts, however, it forms oxyhydroxide precipitates that stain laundry and porcelain. As a result, the recommended limit for iron in domestic water supplies is 0.3 mg/L. These test methods are useful for determining iron in many natural waters.
1.1 These test methods cover the determination of iron in water. Procedures are given for determining total iron, dissolved iron, and ferrous iron. Undissolved iron may be calculated from the total iron and dissolved iron determinations. The test methods are given as follows:
Test Method A—Atomic Absorption,
0.1 to 5.0 mg/L
Test Method B—Atomic Absorption,
5 to 100 μg/L
Test Method C—Photometric
40 to 1000 μg/L
1.2 It is the user's responsibility to ensure the validity of these test methods to waters of untested matrices.
1.3 The chelation-extraction and two former photometric test methods were discontinued. See for historical information.
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in , , and .
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D858 Test Methods for Manganese in Water
D1066 Practice for Sampling Steam
D1129 Terminology Relating to Water
D1193 Specification for Reagent Water
D1687 Test Methods for Chromium in Water
D1688 Test Methods for Copper in Water
D1691 Test Methods for Zinc in Water
D1886 Test Methods for Nickel in Water
D2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
D3370 Practices for Sampling Water from Closed Conduits
D3558 Test Methods for Cobalt in Water
D3559 Test Methods for Lead in Water
D3919 Practice for Measuring Trace Elements in Water by Graphite Furnace Atomic Absorption Spectrophotometry
D4841 Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents
D5673 Test Method for Elements in Water by Inductively Coupled Plasma--Mass Spectrometry
D5810 Guide for Spiking into Aqueous Samples
D5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
E60 Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry
E275 Practice for Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers
ICS Number Code 13.060.50 (Examination of water for chemical substances)
|Link to Active (This link will always route to the current Active version of the standard.)|
ASTM D1068-15, Standard Test Methods for Iron in Water, ASTM International, West Conshohocken, PA, 2015, www.astm.orgBack to Top