SYMPOSIA PAPER Published: 01 January 2000
STP13456S

Sources of Systematic Bias Reflected in an ASTM Collaborative Study on Water in Oil Measured by the Karl Fischer Method

Source

A collaborative study on the precision and bias of the measurement of water in transformer oils indicated that an acceptable level of precision was achieved using the revised ASTM Test Method for Water in Insulating Liquids by Coulometric Karl Fischer Titration (D 1533-96) and a sample size of 7 mL. Analysis of the distribution of the laboratory results indicates the existence of a systematic bias in the accuracy of the measurement which is related to the instrument design, solvent composition, and calibration of the instrument. Additionally, evidence is presented that indicates that a portion of the water in the oils is not titrated by the coulometric method.

Author Information

Margolis, SA
NIST, Gaithersburg, MD
Price: $25.00
Contact Sales
Related
Reprints and Permissions
Reprints and copyright permissions can be requested through the
Copyright Clearance Center
Details
Developed by Committee: D27
Pages: 59–69
DOI: 10.1520/STP13456S
ISBN-EB: 978-0-8031-5427-8
ISBN-13: 978-0-8031-2613-8