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A method has been developed for accurate quantitative determination of additive elements and wear metals in gasoline and diesel fuel in the concentration range of 0 to 50 ppm using inductively coupled plasma atomic emission spectrometry (ICP-AES). This method requires an ICP capable of detecting metals at the 0.02 mg/kg level, and capable of linear calibration over the range of 0.05 to 20.0 mg/kg with a correlation coefficient of 0.9999 or better. No additional ICP-AES accessory or lengthy sample preparation is required. The PerkinElmer Optima 4300 has been shown to meet this requirement.
gasoline, diesel fuel, additive elements, ICP, wear metals, analysis
Ethyl Corporation, Richmond, VA