This test method establishes a standard procedure for rapidly (in 1 h or less) determining the chemical resistance of specimens of protective clothing materials. This test method can be used to rank materials as to their suitability for use with liquids of known or unknown composition.

The breakthrough detection time, permeation rate, or cumulative permeation can be used to identify protective clothing materials that are more likely to limit potential exposures to chemicals. Longer breakthrough detection times and lower cumulative amounts permeated and permeation rates are characteristics of materials that are better barriers to the test chemical.

In general this test method is less sensitive than Test Method F739 coupled with sensitive analytical procedures. In cases where the chemical of concern is highly toxic and contact of even a very small amount with the skin may be detrimental to health, the permeation cup method is not recommended. Use Test Method F739.

Upon permeating the clothing material, the chemical must evaporate in order for a weight loss to occur and permeation to be detected. Consequently, the test method may not be applicable for chemicals having low volatility (that is, vapor pressure). The vapor pressure below which this test method is not applicable has not been determined.

A procedure for assessing volatility is described in Section 10.

The results of this test method are highly dependent on the test temperature. If the objective is to compare different clothing materials, all tests shall be conducted at the same temperature (±3°C).

1. Scope

1.1 This test method measures the barrier effectiveness of a specimen of protective clothing upon continuous contact with a liquid.

1.1.1 Procedure A—For use when a value for the cumulative amount of chemical permeated in 1 h is desired.

1.1.2 Procedure B—For use when breakthrough detection time and permeation rate values are desired.

1.2 Although not addressed herein, the effect of the test chemical on the clothing material can be determined by comparing the weight or other physical properties of the specimen before and after the permeation test.

1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 2.

2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ASTM Standards

D471 Test Method for Rubber Property--Effect of Liquids

D543 Practices for Evaluating the Resistance of Plastics to Chemical Reagents

D751 Test Methods for Coated Fabrics

E105 Practice for Probability Sampling of Materials

F739 Test Method for Permeation of Liquids and Gases through Protective Clothing Materials under Conditions of Continuous Contact

F903 Test Method for Resistance of Materials Used in Protective Clothing to Penetration by Liquids

F1001 Guide for Selection of Chemicals to Evaluate Protective Clothing Materials

Federal Standard

Keywords

chemical protective clothing; liquid permeation; permeation; permeation cup method;

ICS Code

ICS Number Code 13.340.10 (Protective clothing)

Citing ASTM Standards

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