This test method was developed for the determination of nitrogen trichloride in samples of carbon tetrachloride liquid taken from the compressor suction chiller bottoms of chlorine production plants and other places in the plants that may collect and concentrate nitrogen trichloride to levels that could explode. The test method was then modified to measure the lower levels of nitrogen trichloride observed in product liquid chlorine. This test method is sensitive enough to measure the levels of nitrogen trichloride observed in the normal production of liquid chlorine.

This test method for nitrogen trichloride will require the dilution (100:1) of highly concentrated in-process samples to bring them within the working range of the analysis.

1. Scope

1.1 This test method uses high performance liquid chromatography (HPLC) to determine nitrogen trichloride levels in liquid chlorine at the 0.1 to 600 g/g (ppm) range. Solvent samples from chlorine production facilities containing very high concentrations of nitrogen trichloride may be analyzed by dilution with methanol.

1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.

1.3 Review the current material safety data sheet (MSDS) for detailed information concerning toxicity, first aid procedures, and safety precautions.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 8.

2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ASTM Standards

E180 Practice for Determining the Precision of ASTM Methods for Analysis and Testing of Industrial and Specialty Chemicals

E806 Test Method for Carbon Tetrachloride and Chloroform in Liquid Chlorine by Direct Injection (Gas Chromatographic Procedure)

Other Document

Federal Standard

Keywords

chlorine; high performance liquid chromatography; HPLC; nitrogen trichloride; reversed phase;

ICS Code

ICS Number Code 71.040.30 (Chemical reagents)

Citing ASTM Standards

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