Significance and Use
These test methods for the chemical analysis of zinc-nickel alloy coating on sheet steel are primarily intended as referee methods to test such materials for compliance with compositional specifications such as found in Specification A 918, particularly those under the jurisdiction of ASTM Committee A05 on Metallic-Coated Iron and Steel Products. It is assumed that all who use these test methods will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that work will be performed in a properly equipped laboratory under appropriate quality control practices such as those described in Guide E 882.
These test methods must be applied twice, once to each side of the specimen if coating weight and composition are required for both sides of a coated sheet. Two separate specimens are required for this purpose.
1. Scope
1.1 These test methods cover independently the chemical analysis of each surface of zinc-nickel alloy electrolytically coated on steel sheet. The coatings have chemical compositions within the following limits:
| Analyte | Concentration Range |
| Coating Weight | 0.0 to 80 g/m2 |
| Nickel | 7.0 to 17.0 % |
1.2 These test methods are in the following sections:
| Sections |
| Coating Weight, by the Weigh-Strip-Weigh Method (20.0 to 45.0 g/m2) | |
| Nickel by the Atomic Absorption Method (11.0 to 13.5 % of Coating Weight Ranging from 20 to 45 g/m2) | |
1.3 The values stated in SI units are to be regarded as standard. In some cases, exceptions allowed in Practice E 380 are also used.
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
1.4 This test method provides a procedure for determining independently the weight of coating on each surface of zinc-nickel alloy-coated sheet steel, in coating masses from 20 to 45 g/m2 (Note 0).
Note 0The upper limit of the scope has been set at 45 g/m2 because test materials with higher coating weight were not available for testing in accordance with Practice E 173. However, recognizing the simplicity of the weigh-strip-weigh technique, materials with higher coating weights can be tested following this procedure. Users of this test method are cautioned that use of it for coating weight determinations above 45 g/m 2 is not supported by interlaboratory testing.
1.5 This test method covers the determination of nickel in concentrations from 11.0 to 13.5 % in zinc-nickel coatings ().
Note 2The upper limit of the scope has been set at 13.5 % because sufficient test materials containing higher nickel were unavailable in accordance with Practice E 173. However, recognizing the calibration technique of atomic absorption spectrophotometer, materials with higher nickel content may be tested following this procedure. Users of this test method are cautioned that use of it for nickel determination out of the scope is not supported by the interlaboratory testing.
2. Referenced Documents (purchase separately)
The documents listed below are referenced within the subject standard but are not provided as part of the standard.
ASTM Standards
A917 Specification for Steel Sheet, Coated by the Electrolytic Process for Applications Requiring Designation of the Coating Mass on Each Surface (General Requirements)
A918 Specification for Steel Sheet, Zinc-Nickel Alloy Coated by the Electrolytic Process for Applications Requiring Designation of the Coating Mass on Each Surface
D1193 Specification for Reagent Water
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E50 Practices for Apparatus, Reagents, and Safety Precautions for Chemical Analysis of Metals
E135 Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
E173 Practice for Conducting Interlaboratory Studies of Methods for Chemical Analysis of Metals
E663 Practice for Flame Atomic Absorption Analysis
E882 Guide for Accountability and Quality Control in the Chemical Analysis Laboratory
E1024 Guide for Chemical Analysis of Metals and Metal Bearing Ores by Flame Atomic Absorption Spectrophotometry
E1452 Practice for Preparation of Calibration Solutions for Spectrophotometric and for Spectroscopic Atomic Analyses
E1601 Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method
Index Terms
atomic absorption spectrophotometry; coated steel sheet; coating weight; nickel; stripping solution; weigh-strip-weigh; zinc;
ICS Code
ICS Number Code 25.220.40 (Metallic coatings)
DOI: 10.1520/E1659-05
ASTM International is a member of CrossRef.
Citing ASTM Standards
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