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Significance and Use
5.1 The sulfated ash can be used to indicate the concentration of known metal-containing additives in new oils. When phosphorus is absent, barium, calcium, magnesium, sodium and potassium are converted to their sulfates and tin (stannic) and zinc to their oxides (Note 4). Sulfur and chlorine do not interfere, but when phosphorus is present with metals, it remains partially or wholly in the sulfated ash as metal phosphates.
5.2 Because of above inter-element interferences, experimentally obtained sulfated ash values may differ from sulfated ash values calculated from elemental analysis. The formation of such non-sulfated species is dependent on the temperature of ashing, time ashed, and the composition of metal compounds present in oils. Hence, sulfated ash requirement generally should not be used in product specifications without a clear understanding between a buyer and a seller of the unreliability of an ash value as an indicator of the total metallic compound content.4
1.1 This test method covers the determination of the sulfated ash from unused lubricating oils containing additives and from additive concentrates used in compounding. These additives usually contain one or more of the following metals: barium, calcium, magnesium, zinc, potassium, sodium, and tin. The elements sulfur, phosphorus, and chlorine can also be present in combined form.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D482 Test Method for Ash from Petroleum Products
D1193 Specification for Reagent Water
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products
D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
CEN StandardsEN 14213 Heating Fuels--Fatty Acid Methyl Esters (FAME)--Requirements and Test Methods EN 14214 Automotive Fuels--Fatty Acid Methyl Esters (FAME) for Diesel Engines--Requirements and Test Methods
ICS Number Code 75.100 (Lubricants, industrial oils and related products)
UNSPSC Code 15120000(Lubricants and oils and greases and anti corrosives)
ASTM D874-13a, Standard Test Method for Sulfated Ash from Lubricating Oils and Additives, ASTM International, West Conshohocken, PA, 2013, www.astm.orgBack to Top