ASTM D7858 - 13

    Standard Test Method for Determination of Bisphenol A in Soil, Sludge and Biosolids by Pressurized Fluid Extraction and Analyzed by Liquid Chromatography/Tandem Mass Spectrometry

    Active Standard ASTM D7858 | Developed by Subcommittee: D34.01.06

    Book of Standards Volume: 11.04


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    Significance and Use

    5.1 This is a performance based method, and modifications are allowed to improve performance.

    5.1.1 Due to the rapid development of newer instrumentation and column chemistries, changes to the analysis described in this test method are allowed as long as better or equivalent performance data result. Any modifications shall be documented and performance data generated. The user of the data generated by this test method shall be made aware of these changes and given the performance data demonstrating better or equivalent performance.

    5.2 The first reported synthesis of BPA was by the reaction of phenol with acetone by Zincke.7 BPA has become an important high volume industrial chemical used in the manufacture of polycarbonate plastic and epoxy resins. Polycarbonate plastic and resins are used in numerous products including electrical and electronic equipment, automobiles, sports and safety equipment, reusable food and drink containers, electrical laminates for printed circuit boards, composites, paints, adhesives, dental sealants, protective coatings and many other products.8

    5.3 The environmental source of BPA is predominantly from the decomposition of polycarbonate plastics and resins. BPA is not classified as bio-accumulative by the U.S. Environmental Protection Agency and will biodegrade. BPA has been reported to have adverse effects in aquatic organisms and may be released into environmental waters directly at trace levels through landfill leachate and sewage treatment plant effluents. This method has been investigated for use with soil, sludge, and biosolids.

    5.4 The land application of biosolids has raised concerns over the fate of BPA in the environment and a standard method is needed to monitor concentrations. This method has been investigated for use with various soils.

    1. Scope

    1.1 This procedure covers the determination of Bisphenol A (BPA) in soil, sludge, and biosolids. This test method is based upon solvent extraction of a soil matrix by pressurized fluid extraction (PFE). The extract is filtered and analyzed by liquid chromatography/tandem mass spectrometry (LC/MS/MS). BPA is qualitatively and quantitatively determined by this test method.

    1.2 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.3 The Method Detection Limit2 (MDL), electrospray ionization (ESI) mode, and Reporting Range3 for BPA are listed in Table 1.

    TABLE 1 Method Detection Limit and Reporting Range

    Analyte

    ESI Mode

    MDL (PPB)

    Reporting Range (PPB)

    Bisphenol A

    Negative

    2.8

    10-250


    1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.


    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D653 Terminology Relating to Soil, Rock, and Contained Fluids

    D1193 Specification for Reagent Water

    D3694 Practices for Preparation of Sample Containers and for Preservation of Organic Constituents

    D3740 Practice for Minimum Requirements for Agencies Engaged in Testing and/or Inspection of Soil and Rock as Used in Engineering Design and Construction

    D3856 Guide for Management Systems in Laboratories Engaged in Analysis of Water

    D5681 Terminology for Waste and Waste Management

    E2554 Practice for Estimating and Monitoring the Uncertainty of Test Results of a Test Method Using Control Chart Techniques


    ICS Code

    ICS Number Code 13.080.10 (Chemical characteristics of soil)

    UNSPSC Code

    UNSPSC Code 41115711(Liquid chromatography LC columns)


    DOI: 10.1520/D7858-13

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