ASTM D7798 - 13

    Standard Test Method for Boiling Range Distribution of Petroleum Distillates with Final Boiling Points up to 538°C by Ultra Fast Gas Chromatography (UF GC)

    Active Standard ASTM D7798 | Developed by Subcommittee: D02.04.0H

    Book of Standards Volume: 05.04

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    Significance and Use

    5.1 The boiling range distribution of petroleum distillate fractions provides an insight into the composition of feed stocks and products related to petroleum refining processes. A major advantage of the fast analysis time obtained by this test method is increasing product through put and reduced lab testing time by a minimum factor of 3. This gas chromatographic determination of boiling range may be used to replace conventional distillation methods for control of refining operations and for product specification testing with the mutual agreement of interested parties.

    5.2 Boiling range distributions obtained by this test method are essentially equivalent to those obtained by true boiling point (TBP) distillation (see Test Method D2892). They are not equivalent to results from low efficiency distillations such as those obtained with Test Method D86 or D1160.

    1. Scope

    1.1 This test method covers the determination of the boiling range distribution of petroleum products and biodiesel formulations, B5, B10, and B20. It is applicable to petroleum distillates having a final boiling point not greater than 538°C or lower at atmospheric pressure as measured by this test method. The difference between the initial boiling point and the final boiling point shall be greater than 55°C.

    1.2 The test method is not applicable for analysis of petroleum distillates containing low molecular weight components (for example naphthas, reformates, gasolines, full range crude oils). Materials containing heterogeneous mixtures (for example, alcohols, ethers, acids or esters, except biodiesels) or residue are not to be analyzed by this test method. See Test Methods D3710, D7096, D6352, or D7169.

    1.3 This test method uses the principles of simulated distillation methodology. This test method uses gas chromatographic components that allow the entire analysis from sample to sample to occur in 5 min or less. In these instruments the column is heated directly at rates 10–15 times that of a conventional gas chromatograph and thus the analysis time is reduced from sample to sample.

    1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.4.1 Exception—Appendix X1 includes temperatures in Fahrenheit for information only.

    1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D86 Test Method for Distillation of Petroleum Products at Atmospheric Pressure

    D1160 Test Method for Distillation of Petroleum Products at Reduced Pressure

    D2887 Test Method for Boiling Range Distribution of Petroleum Fractions by Gas Chromatography

    D2892 Test Method for Distillation of Crude Petroleum (15-Theoretical Plate Column)

    D3710 Test Method for Boiling Range Distribution of Gasoline and Gasoline Fractions by Gas Chromatography

    D4626 Practice for Calculation of Gas Chromatographic Response Factors

    D6352 Test Method for Boiling Range Distribution of Petroleum Distillates in Boiling Range from 174 to 700C by Gas Chromatography

    D6708 Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material

    D7096 Test Method for Determination of the Boiling Range Distribution of Gasoline by Wide-Bore Capillary Gas Chromatography

    D7169 Test Method for Boiling Point Distribution of Samples with Residues Such as Crude Oils and Atmospheric and Vacuum Residues by High Temperature Gas Chromatography

    E355 Practice for Gas Chromatography Terms and Relationships

    E594 Practice for Testing Flame Ionization Detectors Used in Gas or Supercritical Fluid Chromatography

    E1510 Practice for Installing Fused Silica Open Tubular Capillary Columns in Gas Chromatographs

    ICS Code

    ICS Number Code 75.080 (Petroleum products in general)

    UNSPSC Code

    UNSPSC Code 15101500(Petroleum and distillates); 15101801(Biodiesel)

    DOI: 10.1520/D7798-13

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