ASTM D7458 - 08

    Standard Test Method for Determination of Beryllium in Soil, Rock, Sediment, and Fly Ash Using Ammonium Bifluoride Extraction and Fluorescence Detection

    Active Standard ASTM D7458 | Developed by Subcommittee: D18.01

    Book of Standards Volume: 04.09


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    ASTM D7458

    Significance and Use

    Exposure to beryllium can cause a potentially fatal disease, and occupational exposure limits for beryllium in air and on surfaces have been established to reduce exposure risks to potentially affected workers (2, 3). Measurement of beryllium in matrices such as soil, rock, sediment, and fly ash is important in environmental remediation projects involving beryllium contamination (4) and for establishment of background levels of beryllium at sites where anthropogenic beryllium may have been used (2). Sampling and analytical methods for beryllium are needed in order to meet the challenges relating to exposure assessment and risk reduction. Sampling and analysis methods, such as the procedure described in this test method, are desired in order to facilitate measurements of beryllium that can be used as a basis for management of remediation projects and protection of human health.

    This test method can be used for purposes such as environmental remediation projects where beryllium is a contaminant of concern. It is also useful for characterization of levels of beryllium in soil at sites where beryllium is in mining or manufacturing applications, and for determination of background levels of beryllium in soil.

    Note 1—The quality of the result produced by this standard is dependent on the competence of the personnel performing it, and the suitability of the equipment and facilities used. Agencies that meet the criteria of Practice D 3740 are generally considered capable of competent and objective testing, sampling, inspection, etc. Users of this standard are cautioned that compliance with Practice D 3740 does not in itself assure reliable results. Reliable results depend on many factors; Practice D 3740 provides a means of evaluating some of those factors.

    1. Scope

    1.1 This test method is intended for use in the determination of beryllium in samples of soil, rock, sediment, and fly ash. This test method can be used for purposes such as environmental remediation projects where beryllium is a contaminant of concern. It is also useful for characterization of levels of beryllium in soil at sites where beryllium is in mining or manufacturing applications, and for determination of background levels of beryllium in soil.

    1.2 This test method assumes that samples of soil, rock, sediment, or fly ash are collected using appropriate and applicable ASTM International standard practices.

    1.3 This test method includes a procedure for on-site extraction (dissolution) of beryllium in dilute ammonium bifluoride, followed by analysis of aliquots of the extract solution using a beryllium-specific fluorescent dye.

    1.4 No detailed operating instructions are provided because of differences among various makes and models of suitable fluorometric instruments. Instead, the analyst shall follow the instructions provided by the manufacturer of the particular instrument. This test method does not address comparative accuracy of different devices or the precision between instruments of the same make and model.

    1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.6 All observed and calculated values shall conform to the guidelines for significant digits and rounding established in Practice D 6026.

    1.6.1 The procedures used to specify how data are collected/recorded, or calculated, in this standard are regarded as the industry standard. In addition, they are representative of the significant digits that generally should be retained. The procedures used do not consider material variation, purpose for obtaining the data, special purpose studies, or any considerations for the users objectives; and it is common practice to increase or reduce significant digits of reported data to be commensurate with these considerations. It is beyond the scope of this standard to consider significant digits used in analytical methods for engineering design.

    1.7 This test method contains notes that are explanatory and not part of mandatory requirements of the standard.

    1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards associated with performance of this test method are described in Section 9.


    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D653 Terminology Relating to Soil, Rock, and Contained Fluids

    D1193 Specification for Reagent Water

    D3740 Practice for Minimum Requirements for Agencies Engaged in Testing and/or Inspection of Soil and Rock as Used in Engineering Design and Construction

    D4840 Guide for Sample Chain-of-Custody Procedures

    D5730 Guide for Site Characterization for Environmental Purposes With Emphasis on Soil, Rock, the Vadose Zone and Ground Water

    D6026 Practice for Using Significant Digits in Geotechnical Data

    D7202 Test Method for Determination of Beryllium in the Workplace Using Field-Based Extraction and Optical Fluorescence Detection

    E177 Practice for Use of the Terms Precision and Bias in ASTM Test Methods

    E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method

    E882 Guide for Accountability and Quality Control in the Chemical Analysis Laboratory

    Other Standard

    ENISO8655-2 Piston-Operated Volumetric Pipettes--Part 2: Piston Pipettes Available from American National Standards Institute (ANSI), 25 W. 43rd St., 4th Floor, New York, NY 10036, http://www.ansi.org.


    ICS Code

    ICS Number Code 13.080.10 (Chemical characteristics of soil)

    UNSPSC Code

    UNSPSC Code 11111501(Soil)


    DOI: 10.1520/D7458-08

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