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Significance and Use
5.1 Sulfates and chlorides may be found in filter plugging deposits and fuel injector deposits. The acceptability for use of the fuel components and the finished fuels depends on the sulfate and chloride content.
5.2 Existent and potential inorganic sulfate and total chloride content, as measured by this test method, can be used as one measure of the acceptability of gasoline components for automotive spark-ignition engine fuel use.
1.1 This test method covers an ion chromatographic procedure for the determination of the existent inorganic and potential sulfate and total inorganic chloride content in hydrous and anhydrous denatured ethanol to be used in motor fuel applications. It is intended for the analysis of ethanol samples containing between 0.55 and 20 mg/kg of existent inorganic sulfate, 4.0 to 20 mg/kg of potential inorganic sulfate, and 0.75 to 50 mg/kg of total inorganic chloride.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Material Safety Data Sheets are available for reagents and materials. Review them for hazards prior to usage.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D1193 Specification for Reagent Water
D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products
D5827 Test Method for Analysis of Engine Coolant for Chloride and Other Anions by Ion Chromatography
D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
D6792 Practice for Quality System in Petroleum Products and Lubricants Testing Laboratories
D7318 Test Method for Existent Inorganic Sulfate in Ethanol by Potentiometric Titration
D7319 Test Method for Determination of Existent and Potential Sulfate and Inorganic Chloride in Fuel Ethanol and Butanol by Direct Injection Suppressed Ion Chromatography
Other StandardISO/CEN15492 Ethanol as a Blending Component for Petrol - Determination of Inorganic Chloride - Ion Chromatographic Method Available from International Organization for Standardization (ISO), 1 rue de Varemb, Case postale 56, CH-1211, Geneva 20, Switzerland, http://www.iso.ch.
ICS Number Code 75.160.20 (Liquid fuels)
UNSPSC Code 15101511(Ethanol)
ASTM D7328-13, Standard Test Method for Determination of Existent and Potential Inorganic Sulfate and Total Inorganic Chloride in Fuel Ethanol by Ion Chromatography Using Aqueous Sample Injection, ASTM International, West Conshohocken, PA, 2013, www.astm.orgBack to Top