ASTM D7319 - 13

    Standard Test Method for Determination of Existent and Potential Sulfate and Inorganic Chloride in Fuel Ethanol and Butanol by Direct Injection Suppressed Ion Chromatography

    Active Standard ASTM D7319 | Developed by Subcommittee: D02.03

    Book of Standards Volume: 05.04


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    ASTM D7319

    Significance and Use

    5.1 Sulfates and chlorides can be found in filter plugging deposits and fuel injector deposits. The acceptability for use of the fuel components and the finished fuels depends on the sulfate and chloride content.

    5.2 Existent and potential inorganic sulfate and total chloride content, as measured by this test method, can be used as one measure of the acceptability of gasoline components for automotive spark-ignition engine fuel use.

    1. Scope

    1.1 This test method covers a direct injection ion chromatographic procedure for determining existent and potential inorganic sulfate and total inorganic chloride content in hydrous and anhydrous denatured ethanol and butanol to be used in motor fuel applications. It is intended for the analysis of ethanol and butanol samples containing between 1.0 to 20 mg/kg of existent or potential inorganic sulfate and 1.0 to 50 mg/kg of inorganic chloride.

    Note 1Tertiary butanol is not included in this test method. 1-butanol, 2-butanol, and isobutanol are included in the testing and research report for this test method.

    1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Material Safety Data Sheets are available for reagents and materials. Review them for hazards prior to usage.


    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D1193 Specification for Reagent Water

    D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter

    D4057 Practice for Manual Sampling of Petroleum and Petroleum Products

    D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products

    D5827 Test Method for Analysis of Engine Coolant for Chloride and Other Anions by Ion Chromatography

    D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance

    D6792 Practice for Quality System in Petroleum Products and Lubricants Testing Laboratories

    D7318 Test Method for Existent Inorganic Sulfate in Ethanol by Potentiometric Titration

    D7328 Test Method for Determination of Existent and Potential Inorganic Sulfate and Total Inorganic Chloride in Fuel Ethanol by Ion Chromatography Using Aqueous Sample Injection


    ICS Code

    ICS Number Code 71.040.50 (Physicochemical methods of analysis); 75.160.20 (Liquid fuels)

    UNSPSC Code

    UNSPSC Code 15101511(Ethanol)


    DOI: 10.1520/D7319

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