ASTM D7065 - 11

    Standard Test Method for Determination of Nonylphenol, Bisphenol A, p-tert -Octylphenol, Nonylphenol Monoethoxylate and Nonylphenol Diethoxylate in Environmental Waters by Gas Chromatography Mass Spectrometry

    Active Standard ASTM D7065 | Developed by Subcommittee: D19.06

    Book of Standards Volume: 11.02


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    ASTM D7065

    Significance and Use

    5.1 Nonylphenol3, octylphenol, and bisphenol A have been shown to have toxic effects in aquatic organisms. The source of nonylphenol and octylphenol is prominently from the use of common commercial surfactants. The most widely used surfactant is NPEO which has an average ethoxylate chain of 9 mol of ethoxylate. The ethoxylate chain is readily biodegraded to form NP1EO and NP2EO, nonylphenol carboxylate (NPEC) and, under anaerobic conditions, nonylphenol. Nonylphenol will also biodegrade, but may be released into environmental waters directly at trace levels. This method has been investigated for use with surface water and waste treatment effluent samples and is applicable to these matrices. It has not been investigated for use with salt water or solid sample matrices.

    5.2 The first reported synthesis of BPA was by the reaction of phenol with acetone by Zincke.4 BPA has become an important high volume industrial chemical used in the manufacture of polycarbonate plastics and epoxy resins. Polycarbonate plastic and resins are used in numerous products including electrical and electronic equipment, automobiles, sports and safety equipment, reusable food and drink containers, electrical laminates for printed circuit boards, composites, paints, adhesives, dental sealants, protective coatings and many other products.5 The environmental source of BPA is predominantly from the decomposition of polycarbonate plastics and resins. BPA is not classified as bio-accumulative by the U.S. Environmental Protection Agency and will biodegrade. BPA may be released into the environment waters directly at trace levels through landfill leachate and sewage treatment plant effluents.

    1. Scope

    1.1 This test method covers determination of nonylphenol (NP), nonylphenol ethoxylate (NP1EO), nonylphenol diethoxylate (NP2EO), octylphenol (OP), and bisphenol A (BPA) that are partitioned into organic solvent, separated using gas chromatography and detected with mass selective detection. These compounds or isomer mixtures are qualitatively and quantitatively determined by this method. This method adheres to selected ion monitoring mass spectrometry but full scan mass spectrometry has also been shown to work well under these conditions. Either analysis may be used.

    1.2 The method detection limit (MDL) and reporting limit (RL) for NP, NP1EO, NP2EO, OP, and BPA are listed in Table 1.

    TABLE 1 MDL and Reporting Limits

    Analyte

    MDLA, (μg/L)

    Reporting RangeB (μg/L)

    NP

    0.9

    5.0-80.0

    NP1EO

    1.2

    10.0-160.0

    NP2EO

    1.8

    20.0-320.0

    OP

    0.2

    1.0-16.0

    BPA

    0.3

    1.0-16.0

    A MDL Determined Following The Code of Federal Regulations, 40 CFR Part 136, Appendix B.
    B Lowest Point of the Reporting Range is Calculated from the LV1 Concentration Calibration Standard in Table 4.

    1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.


    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D1193 Specification for Reagent Water

    D3694 Practices for Preparation of Sample Containers and for Preservation of Organic Constituents

    D3856 Guide for Management Systems in Laboratories Engaged in Analysis of Water

    D5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

    D5905 Practice for the Preparation of Substitute Wastewater

    E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method


    ICS Code

    ICS Number Code 71.080.15 (Aromatic hydrocarbons)

    UNSPSC Code

    UNSPSC Code 12191503(Phenols or its substitutes or derivatives)


    DOI: 10.1520/D7065-11

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