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Significance and Use
4.1 The carbon isotope analysis is designed to be an adjunct to other information in determination of biobased content, specifically the manufacturer’s records. It is also a means of verifying the authenticity of a disputed lot of material which may be manufactured by different means, from different raw materials. FTIR or other chemical analysis means will identify the molecule as being ethanol, but not give indication of the source (that is, fossil carbon versus modern carbon). The carbon isotopes will give both indication of source and the presence of a mixture of sources.
4.3 This guide provides for accurate and complete reporting of the sample collection, handling, chain of custody, sample preparation and treatment that allows any independent party to assess the validity of the reported biobased content of the material.
1.1 This guide provides a framework for collecting and handling samples for determination of biobased content of materials by means of the carbon isotope method described in Test Methods D6866. Tests for sampling adequacy based on the standard statistical tools are provided. In addition, reporting of the results, including sampling techniques and handling procedures and chain-of-custody issues are discussed.
1.3 Biobased materials often represent sampling problems specific to a given material, such as heterogeneity, and so forth, which require employment of material-specific sampling methods. The use of specialized sampling methods already accepted and validated by industries that manufacture and/or use the biomaterial is encouraged. However, all sampling techniques, especially non-standard techniques developed for specific materials must be reported in sufficient detail to allow critical assessment of the techniques used.
1.4 Carbon isotope analysis involves thermal processing in presence of oxidants. Compatibility of any given material with Test Methods D6866 must be assessed. Special attention must be given to materials with potential for explosion hazards, such as peroxides, nitrated compounds, azides, and so forth. Examples of peroxide-forming compounds are ethers, some ketones and a number of other compounds.
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory requirements prior to use.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D6852 Guide for Determination of Biobased Content, Resources Consumption, and Environmental Profile of Materials and Products
D6866 Test Methods for Determining the Biobased Content of Solid, Liquid, and Gaseous Samples Using Radiocarbon Analysis
E105 Practice for Probability Sampling of Materials
E122 Practice for Calculating Sample Size to Estimate, With Specified Precision, the Average for a Characteristic of a Lot or Process
Other ReferenceCramer,H., Elements of Probability Theory, Wiley & Sons, NY, 1961
ICS Number Code 19.100 (Non-destructive testing)