ASTM D6784 - 16

    Standard Test Method for Elemental, Oxidized, Particle-Bound and Total Mercury in Flue Gas Generated from Coal-Fired Stationary Sources (Ontario Hydro Method)

    Active Standard ASTM D6784 | Developed by Subcommittee: D22.03

    Book of Standards Volume: 11.07


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    Significance and Use

    5.1 The measurement of particle-bound, oxidized, elemental, and total mercury in stationary-source flue gases provides data that can be used for emissions assessments and reporting, the certification of continuous mercury monitoring systems, regulatory compliance determinations and research programs associated with dispersion modeling, deposition evaluation, human health and environmental impact assessments. Particle-bound, oxidized, and elemental mercury measurements before and after control devices may be necessary for optimizing and evaluating the mercury removal efficiency of emission control technologies.

    5.2 This test method was developed for the measurement of mercury in coal-fired power plants and has been extensively validated for that application. With additional procedures given in this standard, it is also applicable to sources having a flue gas composition with high levels of hydrochloric acid, and low levels of sulfur dioxide.

    1. Scope

    1.1 This test method applies to the determination of elemental, oxidized, particle-bound, and total mercury emissions from coal-fired stationary sources.

    1.2 This test method is applicable to elemental, oxidized, particle-bound, and total mercury concentrations ranging from approximately 0.5 to 100 μg/Nm3.

    1.3 This test method describes equipment and procedures for obtaining samples from effluent ducts and stacks, equipment and procedures for laboratory analysis, and procedures for calculating results.

    1.4 This test method is applicable for sampling elemental, oxidized, and particle-bound mercury in flue gases of coal-fired stationary sources. It may not be suitable at all measurement locations, particularly those with high particulate loadings, as explained in Section 16.

    1.5 Method applicability is limited to flue gas stream temperatures within the thermal stability range of the sampling probe and filter components.

    1.6 The values stated in SI units are to be regarded as the standard. The values in parentheses are for information only.

    1.7 This standard requires users to be familiar with EPA stack-gas sampling procedures as stated in EPA Methods 1–4, Method 5, and Method 17.

    1.8 The method requires a high level of experience and quality control both in the field testing and analytical procedures in order to obtain high quality data.

    1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.


    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D1193 Specification for Reagent Water

    D1356 Terminology Relating to Sampling and Analysis of Atmospheres

    D2986 Practice for Evaluation of Air Assay Media by the Monodisperse DOP (Dioctyl Phthalate) Smoke Test

    D3154 Test Method for Average Velocity in a Duct (Pitot Tube Method)

    D3685/D3685M Test Methods for Sampling and Determination of Particulate Matter in Stack Gases

    E1 Specification for ASTM Liquid-in-Glass Thermometers


    ICS Code

    ICS Number Code 13.040.40 (Stationary source emissions)

    UNSPSC Code

    UNSPSC Code 77121500(Air pollution); 77101505(Environmental monitoring)


    Referencing This Standard
    Link Here
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    DOI: 10.1520/D6784-16

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    Citation Format

    ASTM D6784-16, Standard Test Method for Elemental, Oxidized, Particle-Bound and Total Mercury in Flue Gas Generated from Coal-Fired Stationary Sources (Ontario Hydro Method), ASTM International, West Conshohocken, PA, 2016, www.astm.org

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