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Significance and Use
4.1 Gas chromatography with sulfur selective detection provides a rapid means to identify and quantify sulfur compounds in various petroleum feeds and products. Often these materials contain varying amounts and types of sulfur compounds. Many sulfur compounds are odorous, corrosive to equipment, and inhibit or destroy catalysts employed in downstream processing. The ability to speciate sulfur compounds in various petroleum liquids is useful in controlling sulfur compounds in finished products and is frequently more important than knowledge of the total sulfur content alone.
1.1 This test method covers the determination of volatile sulfur-containing compounds in light petroleum liquids. This test method is applicable to distillates, gasoline motor fuels (including those containing oxygenates) and other petroleum liquids with a final boiling point of approximately 230°C (450°F) or lower at atmospheric pressure. The applicable concentration range will vary to some extent depending on the nature of the sample and the instrumentation used; however, in most cases, the test method is applicable to the determination of individual sulfur species at levels of 0.1 to 100 mg/kg.
1.2 The test method does not purport to identify all individual sulfur components. Detector response to sulfur is linear and essentially equimolar for all sulfur compounds within the scope (1.1) of this test method; thus both unidentified and known individual compounds are determined. However, many sulfur compounds, for example, hydrogen sulfide and mercaptans, are reactive and their concentration in samples may change during sampling and analysis. Coincidently, the total sulfur content of samples is estimated from the sum of the individual compounds determined; however, this test method is not the preferred method for determination of total sulfur.
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D2622 Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry
D3120 Test Method for Trace Quantities of Sulfur in Light Liquid Petroleum Hydrocarbons by Oxidative Microcoulometry
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4307 Practice for Preparation of Liquid Blends for Use as Analytical Standards
D4626 Practice for Calculation of Gas Chromatographic Response Factors
ICS Number Code 75.160.20 (Liquid fuels)