ASTM D5463 - 13

    Standard Guide for Use of Test Kits to Measure Inorganic Constituents in Water

    Active Standard ASTM D5463 | Developed by Subcommittee: D19.05

    Book of Standards Volume: 11.01


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    Significance and Use

    5.1 Inorganic constituents in water and wastewater must be identified and measured to support effective water quality monitoring and control programs. Currently, one of the simplest, most practical and cost effective means of accomplishing this is through the use of chemical test kits and refills. A more detailed discussion is presented in ASTM STP 1102.5

    5.2 Test kits have been accepted for many applications, including routine monitoring, compliance reporting, rapid screening, trouble investigation, and tracking contaminant source.

    5.3 Test kits offer time-saving advantages to the user. They are particularly appropriate for field use and usually are easy to use. Users do not need to have a high level of technical expertise. Relatively unskilled staff can be trained to make accurate determinations using kits that include a premixed liquid reagent, premeasured reagent (tablets, powders, or glass ampoules), and premeasured sample (evacuated glass ampoules).

    1. Scope

    1.1 This guide covers general considerations for the use of test kits for quantitative determination of analytes in water and wastewater. Test kits are available from various manufacturers for the determination of a wide variety of analytes in drinking water, surface or ground waters, domestic and industrial feedwaters and wastes, and water used in power generation and steam raising. See Table 1 for a listing of some of the types of kits that are available for various inorganic analytes in water.2

    TABLE 1 Availability and Types of Test Kits

    Analyte

    Kit Methodology A

    Acidity

    T

    Alkalinity

    C, P, T

    Aluminum

    C, P

    Ammonia

    C, P

    Boron

    C, P

    Bromine

    C, P, T

    Cadmium

    C

    Calcium

    P, T

    Carbon dioxide

    T

    Chloride

    A, C, P, T

    Chlorine

    C, P, T

    Chlorine dioxide

    C, P, T

    Chromium (III)

    C

    Chromium (VI)

    C, P, T

    Cobalt

    C

    Copper

    C, P, T

    Cyanide

    C, P, T

    Fluoride

    P

    Hardness

    C, GNG, P, T

    Hydrazine

    C, P

    Hydrogen peroxide

    C, P, T

    Iodine

    C, P, T

    Iron

    C, P

    Lead

    C, P

    Manganese

    C, P

    Magnesium

    C, T

    Molybdate

    C, P, T

    Nickel

    C, P

    Nitrate

    C, P

    Nitrite

    C, P, T

    Oxygen (dissolved)

    C, P, T

    Ozone

    C, P

    Permanganate

    C, T

    pH

    C, P

    Phosphate

    C, P

    Silica

    C, P

    Silver

    P

    Sulfate

    A, C, P, T

    Sulfide

    C, P, T

    Sulfite

    C, P, T

    Thiocyanate

    C

    Tin

    C

    Vanadium

    C

    Zinc

    C, P, T

    A Kit Methodology: A = appearance/turbidity, C = visual colorimetric, GNG = go no go, P = photometric, and T = titrimetric.

    1.2 Ranges, detection limits, sensitivity, accuracy, and susceptibility to interferences vary from kit to kit, depending on the methodology selected by the manufacturer. In some cases, kits are designed to replicate exactly an official test method of a standard-setting organization such as the Association of Official Analytical Chemists (AOAC), American Public Health Association (APHA), ASTM, or the U.S. Environmental Protection Agency (USEPA). In other cases, minor modifications of official test methods are made for various reasons, such as to improve performance, operator convenience, or ease of use. Adjustments may be made to sample size, reagent volumes and concentrations, timing, and details of the analytical finish. In yet other cases, major changes may be made to the official test method, such as the omission of analytical steps, change of the analytical finish, omission of reagents, or substitution of one reagent for another. Reagents in test kits are often combined to obtain a fewer number and make the test easier to use. Additives may also be used to minimize interferences and to make the reagent more stable with time. A kit test method may be based on a completely different technology, not approved by any official or standard-setting organization. Combinations of test kits—multi-parameter test kits—may be packaged to satisfy the requirements of a particular application conveniently. The test kits in such combination products may be used to make dozens of determinations of several parameters.

    1.3 Test kit reagent refills are commonly available from manufacturers. Refills permit cost savings through reuse of the major test kit components.

    1.4 Because of the wide differences among kits and methodologies for different analytes, universal instructions cannot be provided. Instead, the user should follow the instructions provided by the manufacturer of a particular kit.

    1.5 A test kit or kit component should not be used after the manufacturer's expiration date; it is the user's responsibility to determine that the performance is satisfactory.

    1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see Section 10.


    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D1129 Terminology Relating to Water

    D1193 Specification for Reagent Water

    D3370 Practices for Sampling Water from Closed Conduits

    D4453 Practice for Handling of High Purity Water Samples

    D4691 Practice for Measuring Elements in Water by Flame Atomic Absorption Spectrophotometry

    D5810 Guide for Spiking into Aqueous Samples

    D5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

    E178 Practice for Dealing With Outlying Observations

    E275 Practice for Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers

    E958 Practice for Estimation of the Spectral Bandwidth of Ultraviolet-Visible Spectrophotometers


    ICS Code

    ICS Number Code 13.060.50 (Examination of water for chemical substances)

    UNSPSC Code

    UNSPSC Code


    DOI: 10.1520/D5463-13

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