ASTM D5222 - 08

    Standard Specification for High Fire-Point Mineral Electrical Insulating Oils

    Active Standard ASTM D5222 | Developed by Subcommittee: D27.01

    Book of Standards Volume: 10.03


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    Abstract

    This specification describes a high fire-point mineral oil based electrical insulating fluid, for use as a dielectric and cooling medium in new and existing power and distribution electrical apparatus, such as transformers and switchgear. The material discussed here is miscible with other petroleum based insulating oils, and may not be miscible with electrical insulating liquids of non-petroleum origin. The insulating oils shall be compatible with typical material of construction of existing apparatus and will satisfactorily maintain its functional characteristic in its application. This specification applies only to new insulating material oil as received prior to any processing. Sampled specimens shall undergo appropriate tests, and shall conform correspondingly to specified physical (appearance upon visual examination, color in ASTM units, fire point, flash point, aniline point, interfacial tension, pour point, relative density, and kinematic viscosity), electrical (dielectric breakdown voltage, gassing tendency, and dissipation factor), and chemical (corrosion behavior against sulfur, inorganic chlorides and sulfates content, acid number, water content, oxidation stability, oxidation inhibitor content, and PCB content) property requirements.

    This abstract is a brief summary of the referenced standard. It is informational only and not an official part of the standard; the full text of the standard itself must be referred to for its use and application. ASTM does not give any warranty express or implied or make any representation that the contents of this abstract are accurate, complete or up to date.

    Significance and Use

    1. Scope

    1.1 This specification describes a high fire-point mineral oil based insulating fluid, for use as a dielectric and cooling medium in new and existing power and distribution electrical apparatus, such as transformers and switchgear.

    1.2 High fire-point insulating oil differs from conventional mineral insulating oil by possessing a fire-point of at least 300°C. High fire-point mineral insulating oils are also referred to as less flammable mineral insulating oils.This property is necessary in order to comply with certain application requirements of the National Electrical Code (Article 450-23) or other agencies. The material discussed in this specification is miscible with other petroleum based insulating oils. Mixing high fire-point liquids with lower fire point hydrocarbon insulating oils (for example, Specification D 3487 mineral oil) may result in fire points of less than 300°C.

    1.3 This specification is intended to define a high fire-point electrical mineral insulating oil that is compatible with typical material of construction of existing apparatus and will satisfactorily maintain its functional characteristic in its application in this application. The material described in this specification may not be miscible with electrical insulating liquids of non-petroleum origin. The user should contact the manufacturer of the high fire-point insulating oil for guidance in this respect.

    1.4 This specification applies only to new insulating material oil as received prior to any processing. Information on in-service maintenance testing is available in appropriate guides. The user should contact the manufacturers of the equipment or oil if questions of recommended characteristics or maintenance procedures arise.


    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D92 Test Method for Flash and Fire Points by Cleveland Open Cup Tester

    D97 Test Method for Pour Point of Petroleum Products

    D117 Guide for Sampling, Test Methods, and Specifications for Electrical Insulating Oils of Petroleum Origin

    D445 Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (and Calculation of Dynamic Viscosity)

    D611 Test Methods for Aniline Point and Mixed Aniline Point of Petroleum Products and Hydrocarbon Solvents

    D664 Test Method for Acid Number of Petroleum Products by Potentiometric Titration

    D877 Test Method for Dielectric Breakdown Voltage of Insulating Liquids Using Disk Electrodes

    D878 Test Method for Inorganic Chlorides and Sulfates in Insulating Oils

    D923 Practices for Sampling Electrical Insulating Liquids

    D924 Test Method for Dissipation Factor (or Power Factor) and Relative Permittivity (Dielectric Constant) of Electrical Insulating Liquids

    D971 Test Method for Interfacial Tension of Oil Against Water by the Ring Method

    D974 Test Method for Acid and Base Number by Color-Indicator Titration

    D1275 Test Method for Corrosive Sulfur in Electrical Insulating Oils

    D1298 Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method

    D1500 Test Method for ASTM Color of Petroleum Products (ASTM Color Scale)

    D1524 Test Method for Visual Examination of Used Electrical Insulating Oils of Petroleum Origin in the Field

    D1533 Test Method for Water in Insulating Liquids by Coulometric Karl Fischer Titration

    D1816 Test Method for Dielectric Breakdown Voltage of Insulating Oils of Petroleum Origin Using VDE Electrodes

    D2112 Test Method for Oxidation Stability of Inhibited Mineral Insulating Oil by Pressure Vessel

    D2300 Test Method for Gassing of Electrical Insulating Liquids Under Electrical Stress and Ionization (Modified Pirelli Method)

    D2440 Test Method for Oxidation Stability of Mineral Insulating Oil

    D2668 Test Method for 2,6-di-tert-Butyl- p-Cresol and 2,6-di-tert-Butyl Phenol in Electrical Insulating Oil by Infrared Absorption

    D2864 Terminology Relating to Electrical Insulating Liquids and Gases

    D3487 Specification for Mineral Insulating Oil Used in Electrical Apparatus

    D4059 Test Method for Analysis of Polychlorinated Biphenyls in Insulating Liquids by Gas Chromatography

    D4768 Test Method for Analysis of 2,6-Ditertiary-Butyl Para-Cresol and 2,6-Ditertiary-Butyl Phenol in Insulating Liquids by Gas Chromatography

    National Fire Protection Association Standards

    NationalElectricalCo Article 450-23 Available from the National Fire Protection Association, Batterymarch Park, Quincy, MA 02269.

    Institute of Electrical and Electronics Engineers Standard

    C57.121 Guide for Acceptance and Maintenance of Less-Flammable Hydrocarbon Fluids and its Maintenance in Transformers Available from the Institute of Electrical and Electronics Engineers, Inc. 345 E. 47th St., New York, NY 10017-2394.


    ICS Code

    ICS Number Code 29.040.10 (Insulating oils)

    UNSPSC Code

    UNSPSC Code 15121505(Transformer oil or insulating oil)


    DOI: 10.1520/D5222-08

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