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Significance and Use
5.1 Vapor pressure is a very important physical property of volatile liquids.
5.2 The vapor pressure of gasoline and gasoline-oxygenate blends is regulated by various government agencies.
5.3 Specifications for volatile petroleum products generally include vapor pressure limits to ensure products of suitable volatility performance.
5.4 This test method is more precise than Test Method D4953, uses a small sample size (1 mL to 10 mL), and requires about 7 min to complete the test.
1.1 This test method covers the use of automated vapor pressure instruments to determine the total vapor pressure exerted in vacuum by air-containing, volatile, liquid petroleum products, including automotive spark-ignition fuels with or without oxygenates (see Note 1). This test method is suitable for testing samples with boiling points above 0 °C (32 °F) that exert a vapor pressure between 7 kPa and 130 kPa (1.0 psi and 18.6 psi) at 37.8 °C (100 °F) at a vapor-to-liquid ratio of 4:1. Measurements are made on liquid sample sizes in the range from 1 mL to 10 mL. No account is made for dissolved water in the sample.
1.1.1 Some gasoline-oxygenate blends may show a haze when cooled to 0 °C to 1 °C. If a haze is observed in 8.5, it shall be indicated in the reporting of results. The precision and bias statements for hazy samples have not been determined (see Note 15).
1.2 This test method is suitable for calculation of the dry vapor pressure equivalent (DVPE) of gasoline and gasoline-oxygenate blends by means of a correlation equation (see Eq 1 in 14.2). The calculated DVPE very closely approximates the dry vapor pressure that would be obtained on the same material when tested by Test Method D4953.
1.3 The values stated in SI units are regarded as standard. The inch-pound units given in parentheses are provided for information only.
1.4 WARNING—Mercury has been designated by many regulatory agencies as a hazardous material that can cause central nervous system, kidney and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury containing products. See the applicable product Material Safety Data Sheet (MSDS) for details and EPA’s website – http://www.epa.gov/mercury/faq.htm - for additional information. Users should be aware that selling mercury and/or mercury containing products into your state or country may be prohibited by law.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific safety warning statements, see 7.2 through 7.8.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D2892 Test Method for Distillation of Crude Petroleum (15-Theoretical Plate Column)
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4953 Test Method for Vapor Pressure of Gasoline and Gasoline-Oxygenate Blends (Dry Method)
D5798 Specification for Ethanol Fuel Blends for Flexible-Fuel Automotive Spark-Ignition Engines
D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
D6377 Test Method for Determination of Vapor Pressure of Crude Oil: VPCRx (Expansion Method)
D6378 Test Method for Determination of Vapor Pressure (VPX) of Petroleum Products, Hydrocarbons, and Hydrocarbon-Oxygenate Mixtures (Triple Expansion Method)
D7717 Practice for Preparing Volumetric Blends of Denatured Fuel Ethanol and Gasoline Blendstocks for Laboratory Analysis
IP StandardIP481 Test Method for Determination of the Air Saturated Vapour Pressure (ASVP) of Crude Oil Available from the Energy Institute, 61 New Cavendish St., London, WIG 7AR, U.K.
ICS Number Code 75.080 (Petroleum products in general)
UNSPSC Code 15101500(Petroleum and distillates)
ASTM D5191-13, Standard Test Method for Vapor Pressure of Petroleum Products (Mini Method), ASTM International, West Conshohocken, PA, 2013, www.astm.orgBack to Top