Significance and Use
Chloride ion is under regulation in waste water, and must, therefore, be measured accurately. It is highly detrimental to high-pressure boiler systems and to stainless steel, so monitoring is essential for prevention of damage. Chloride analysis is widely used as a tool for estimating the cycles of concentration, such as in cooling tower applications. Processing waters and pickling solutions used in the food processing industries also require dependable methods of analysis for chloride.
1.1 These test methods cover the determination of chloride ion in water, wastewater (Test Method C only), and brines. The following three test methods are included:
|Test Method A (Mercurimetric Titration)||7 to14|
|Test Method B (Silver Nitrate Titration)||15 to 21|
|Test Method C (Ion-Selective Electrode Method)||22 to 29|
1.2 Test Methods A, B, and C were validated under Practice D2777 – 77, and only Test Method B conforms also to Practice D2777 – 86. Refer to Sections 14, 21, and 29 for further information.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For a specific hazard statement, see 26.1.1.
1.5 A former colorimetric test method was discontinued. Refer to Appendix X1 for historical information.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D1066 Practice for Sampling Steam
D1129 Terminology Relating to Water
D1193 Specification for Reagent Water
D2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
D3370 Practices for Sampling Water from Closed Conduits
D4127 Terminology Used with Ion-Selective Electrodes
D5810 Guide for Spiking into Aqueous Samples
D5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
E200 Practice for Preparation, Standardization, and Storage of Standard and Reagent Solutions for Chemical Analysis
analysis; chloride; electrode; titrametric; water;
ICS Number Code 13.060.50 (Examination of water for chemical substances)
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Citing ASTM Standards
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